The following mechanism has been proposed for the decomposition of ozone in the atmosphere:(1) O3 → O2 + O and its reverse (k1, k1)(2) O + O3 → O2 + O2 (k2; the reverse reaction is negligibly slow)Use the steady-state approximation, with O treated as the intermediate, to find an expression for the rate of decomposition of O2. Show that if step 2 is slow, then the rate is secondorder in O3 and -1 order in O2.
The following mechanism has been proposed for the decomposition of ozone in the atmosphere:(1) O3 → O2 + O and its reverse (k1, k1)(2) O + O3 → O2 + O2 (k2; the reverse reaction is negligibly slow)Use the steady-state approximation, with O treated as the intermediate, to find an expression for the rate of decomposition of O2. Show that if step 2 is slow, then the rate is secondorder in O3 and -1 order in O2.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The following mechanism has been proposed for the decomposition of ozone in the atmosphere:
(1) O3 → O2 + O and its reverse (k1, k1)
(2) O + O3 → O2 + O2 (k2; the reverse reaction is negligibly slow)
Use the steady-state approximation, with O treated as the intermediate, to find an expression for the rate of decomposition of O2. Show that if step 2 is slow, then the rate is secondorder in O3 and -1 order in O2.
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