The following is intended for students who have already covered IR spectroscopy (Chapter 14). Consider the figure shown in Problem 7.91: Ph Ph ROH -Br Ph- -OR Ph Ph Ph 2 Ph = 3- 2a: R = H 2b: R= CH3 2c: R = CH2CH3 1 IR spectroscopy is an ideal tool for monitoring the conversion of 1 to 2a, while other forms of spectroscopy will be better suited for monitoring the conversion of 1 to 2b or 1 to 2c. Select the reasons why IR is an ideal tool ONLY for conversion of 1 to 2a. Because the O-H absorbance is in the fingerprint region, it is the best way to identify the product. O The CH3 group absorbs only in the fingerprint region so it is hard to identify. O An OH absorbance is diagnostically useful but C-Br and C-O absorbances are in the fingerprint region. C-Br and C-O absorbances are diagnostically useful but the O-H absorbance is in the fingerprint region.

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Chapter1: Chemical Foundations
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The following is intended for students who have already covered IR spectroscopy (Chapter 14). Consider the figure shown in Problem 7.91:
Ph
Ph
ROH
Br
Ph-
-OR
Ph
Ph
Ph
2
Ph =
2a: R = H
1
2b: R = CH3
2c: R = CH2CH3
IR spectroscopy is an ideal tool for monitoring the conversion of 1 to 2a, while other forms of spectroscopy will be better suited for monitoring the conversion of 1 to 2b or 1 to 2c.
Select the reasons why IR is an ideal tool ONLY for conversion of 1 to 2a.
Because the O-H absorbance is in the fingerprint region, it is the best way to identify the product.
The CH3 group absorbs only in the fingerprint region so it is hard to identify.
An OH absorbance is diagnostically useful but C-Br and C-O absorbances are in the fingerprint region.
C-Br and C-O absorbances are diagnostically useful but the O-H absorbance is in the fingerprint region.
Transcribed Image Text:The following is intended for students who have already covered IR spectroscopy (Chapter 14). Consider the figure shown in Problem 7.91: Ph Ph ROH Br Ph- -OR Ph Ph Ph 2 Ph = 2a: R = H 1 2b: R = CH3 2c: R = CH2CH3 IR spectroscopy is an ideal tool for monitoring the conversion of 1 to 2a, while other forms of spectroscopy will be better suited for monitoring the conversion of 1 to 2b or 1 to 2c. Select the reasons why IR is an ideal tool ONLY for conversion of 1 to 2a. Because the O-H absorbance is in the fingerprint region, it is the best way to identify the product. The CH3 group absorbs only in the fingerprint region so it is hard to identify. An OH absorbance is diagnostically useful but C-Br and C-O absorbances are in the fingerprint region. C-Br and C-O absorbances are diagnostically useful but the O-H absorbance is in the fingerprint region.
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