Which of the following molecules will have some of the characteristics of the IR spectrum below? T% 100 Br 90 or OH 3500 N=C=N 3087 3033 HO HCI 3000 2921 Br 2500 cm-1 1727 2000 oro a
Which of the following molecules will have some of the characteristics of the IR spectrum below? T% 100 Br 90 or OH 3500 N=C=N 3087 3033 HO HCI 3000 2921 Br 2500 cm-1 1727 2000 oro a
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:### Infrared (IR) Spectrum Analysis
#### Question:
Which of the following molecules will have some of the characteristics of the IR spectrum below?
#### IR Spectrum:
- **Transmittance (T%) vs. Wavenumber (cm⁻¹) Graph:**
- **Peaks Identified:**
- **3087 cm⁻¹**: Could indicate the presence of C-H stretches, typical for aromatic compounds or alkenes.
- **3033 cm⁻¹**: Another potential C-H stretch, often seen in aromatic hydrocarbon regions.
- **2921 cm⁻¹**: Typically corresponds to C-H stretches found in aliphatic compounds.
- **1727 cm⁻¹**: Indicative of C=O stretches, commonly found in carbonyl groups such as those in ketones and aldehydes.
- The spectrum itself represents a characteristic pattern observed in infrared spectroscopy, used to determine functional groups present within a molecule based on absorption peaks.
#### Molecules to Analyze:
1. **Molecule 1:**
- Contains a brominated aromatic ring with a carboxylic acid group (Br, C=O, and OH).
2. **Molecule 2:**
- Phenol derivative, incorporating a hydroxyl group (OH) on an aromatic ring.
3. **Molecule 3:**
- Contains a long aliphatic chain with cyano groups, N=C=N functionality.
4. **Molecule 4:**
- An ester with bromoester and phenyl groups, also containing a carbonyl group.
5. **Molecule 5:**
- Pyridine derivative, with a possible nitrogen-containing aromatic heterocycle.
#### Interpretation:
Based on the IR spectrum:
- The peak at 1727 cm⁻¹ suggests the presence of a carbonyl group (C=O).
- The peaks at 3087 cm⁻¹ and 3033 cm⁻¹ suggest the presence of aromatic C-H stretches.
- The peak at 2921 cm⁻¹ is typical of aliphatic C-H stretches.
**The molecule most likely matching the IR spectrum is Molecule 4**, which contains both aromatic and ester (carbonyl) features.
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