The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: AsO33- + 2 Ce4+ + H20 AsO43- + 2 Ce3+ + 2 H+ Experiment [Aso33-lo, M [Ce4+]o, M Initial Rate, M s-1 1 2.13x10-2 0.371 1.67x10-3 2 4.26x10-2 0.371 3.33x10-3 3 2.13x10-2 0.742 6.66x10-3 4 4.26x10-2 0.742 1.33x10-2 Complete the rate law for this reaction in the box below. Use the form k[A]m[B]™ , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 form or n. Rate = From these data, the rate constant is M-2s-1.

The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: AsO33- + 2 Ce4+ + H20 AsO43- + 2 Ce3+ + 2 H+ Experiment [Aso33-lo, M [Ce4+]o, M Initial Rate, M s-1 1 2.13x10-2 0.371 1.67x10-3 2 4.26x10-2 0.371 3.33x10-3 3 2.13x10-2 0.742 6.66x10-3 4 4.26x10-2 0.742 1.33x10-2 Complete the rate law for this reaction in the box below. Use the form k[A]m[B]™ , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 form or n. Rate = From these data, the rate constant is M-2s-1.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: The aquation of tris(1,10-phenanthroline)iron(II) in acid solution takes place according to the…

A: Given :- Activation Energy = 126KJ/mol Rate constant at 30℃ = 9.8×10-3 min-1 To find :- Rate…

Q: The following initial rate data are for the reaction of hypochlorite ion with iodide ion in 1 M…

Q: 4-chem The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in…

Q: None

A: Analyzing the Data:Compare rates 1 and 3:(Ce3+)0 is constant (1.0 × 10^-2).The initial rate remains…

Q: The aquation of tris(1,10-phenanthroline)iron(II) in acid solution takes place according to the…

Q: The rate constant for the first order decomposition of N2O5 is given by the following equation: k =…

Q: Step 1: Ag*(aq) + Ce*(aq) Ag²"(aq) + Ce (aq) Step 2: TI(aq) + Ag2 (aq) →TI2*(aq) + Ag*(aq) Step 3:…

A: 1. Catalyst is a substance which is used in reaction to increase the rate and remain unchaged in…

Q: The following initial rate data are for the reduction of nitric oxide with hydrogen: 2 NO + 2 H2N2…

Q: The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous…

Q: The rate of the reaction: CH;COOC,Hs(aq) + OH'(aq) → CH;COO"(aq) + CH;OH(aq) was measured at several…

Q: After 57.0 min, 24.0% of a compound has decomposed. What is the half-life of this reaction assuming…

A: For the first-order kinetics:…

Q: The reduction of nitric oxide with hydrogen 2 NO + 2 H2 N2 + 2 H20 is second order in NO and third…

A: The relation between the concentration of the reactants and the rate of reaction is expressed by the…

Q: B SC forward rate constant: ka, backward rate constant: kb Reactions are 1st order in both…

A: When the rate of forward reaction is equal to the rate of reverse reaction , then the state of…

Q: The following initial rate data are for the reaction of hypochlorite ion with iodide ion in 1 M…

A: We know that Rate constant : Rate constant is the proportionality constant in the equation that…

Q: In the presence of excess thiocyanate ion, SCN, the following reaction is first order in…

A: (a) For the first order reaction half life is given as, t1/2 = 0.693/K where,…

Q: The following initial rate data are for the reaction of nitrogen dioxide with fluorine: Experiment…

A: Answer:Power of the concentration term of a reactant in rate law is equal to the order of reaction…

Q: The rate constant of reaction A^ m+ + B^n--C is measured in two solution of ionic strength 0,16 M…

A: The objective of the question is to find the product of charges in a chemical reaction given the…

Q: Given the following data in the chart and the graph provided below identify the k (rate constant)…

A: The given graph is plotted between time on the x-axis and volume difference on the y-axis. An…

Q: e activation energy for the gas phase isomerization of cis-2-butene is 75.3 cis-CH3 CH=CHCH3 →…

A: Activation energy (Ea)= 75.3 KJ Rate constant (K1)= 1.92×10-4 s-1 Temperature (T1)= 978K Rate…

Q: The rate constant of reaction A+B →C is measured in two solution of ionic strength 0.36 M and 0.09…

A: The objective of the question is to find the product of charges in a chemical reaction given the…

Q: The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous…

A: The sum of the exponent term in the rate law for a chemical reaction is known as the order of the…

Q: The following initial rate data are for the reaction of mercury(II) chloride with oxalate ion: 2…

A: General Chemistry question Explanation:Approach to solving the question: General approach Detailed…

Q: The following results were obtained during kinetic studies of the reaction 2A+B → Products…

A: We will first find out the rate law of the reaction from the given three experiments. From that we…

Q: The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous…

Q: Use the References to access important values if needed for this question. For the gas phase…

A: Given: At temperature, T1= 540 K The rate constant, k1=2.12×10-4 s-1 At temperature, T2= 585 K The…

Q: The reaction A + B → Cwas studied and the following results were obtained. What is the overall order…

A: The reaction given is A + B --------> C The rate law of any reaction depends only on the…

Q: The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous…

A: The objective of the question is to determine the rate and rate constant of the reaction.The rate…

Q: For the gas phase decomposition of difluoroperoxide, F2O2F2+02 the rate constant at 238 Kis 6.99 x…

Q: The activation energy for the gas phase decomposition of trichloroethane is 200 kJ. CH3CCI3CH2=CCI2…

Q: The following initial rate data are for the reaction of mercury(II) chloride with oxalate ion: 2…

A: Rate=9.282×10−3[HgCl2][C2O4−2]2Explanation:

Q: Given that the rate constant is 4.0x 10^-4 M^-1s^-1 at 25.0 C and that the rate constant is 2.6 x…

Q: The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous…

Question

The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution:
AsO33- + 2 Ce4+ + H2O-
→ASO43- + 2 Ce3+ + 2 H+
Experiment
[AsO33"lo, M
[Ce4+]o, M
Initial Rate, M s-1
1
2.13x10-2
0.371
1.67x10-3
4.26x10-2
0.371
3.33x10-3
3
2.13x10-2
0.742
6.66x10-3
4
4.26x10-2
0.742
1.33x10-2
Complete the rate law for this reaction in the box below.
Use the form k[A]™[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n.
Rate =
From these data, the rate constant is
M-2s-1.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step 5

Trending now

This is a popular solution!

Step by step

Solved in 5 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The following initial rate data are for the reaction of hypochlorite ion with iodide ion in 1 M aqueous hydroxide solution: OCI+I → OI+ CI Experiment [OC]o, M [Ilo, M Initial Rate, M. s-¹ 0.00135 0.00173 1.56 × 10-4 0.00135 0.00347 3.12 x 10-4 0.00271 0.00173 3.12 x 10-4 0.00271 0.00347 6.26 × 10-4 1 2 3 4 Complete the rate law for this reaction in the box below. Use the form k[A] [B]", where '1' is understood for m or ŉ and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. Rate = k= M-¹.s-¹
The following initial rate data are for the reaction of hypochlorite ion with iodide ion in IM aqueous hydroxide solution: OCI+T> or + CI 1. Experiment [OCI] Rate 1 3.48x 103 5.05 x 103 1.01 x 10-2 5.05 x 103 1.01 x 102 1.34 x 10-3 2.68 x 103 2.68 x 10-3 5.36 x 103 2 3.48 x 103 6.97 x 10-3 6.97 x 103 4. a) What is the rate law equation? b) Determinek (give the numerical value). c) What is the rate of the above reaction when [OCI-]= 0.224 M and [I-]= 0.125 M?
The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: Aso,3 + 2 Ce** + H20-Aso,3 + 2 Ce3* + 2 H* Initial Rate, M Experiment [Aso,3-], M [Ce**1, M Is 8.53x104 1.71x10-3 3.41x103 6.83x103 1 3.61x10-2 0.204 7.22x10-2 3.61x102 7.22x10-2 2 0.204 3 0.408 14 0.408 Complete the rate law for this reaction in the box below. Use the form k[A]™[B]" , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Rate = From these data, the rate constant is M2s1.
A reaction occurs in two steps with E₂1 = 40 kmol-1 and E₂2 = 25 kJ mol-1. The first step is reversible with E₂-1 = 10 kJ mol-1. If the enthalpy change for the overall reaction is -27 kJ mol-1, then what is the activation energy (kJ mol-¹) for the reverse of step 2? 47 30 O 65 82 55
The aquation of tris-(1,10-phenanthroline) iron(II) in acid solution takes place according to the equation: Fe(phen),2+ + 3 H3O* + 3 H20→ Fe(H,O),2* + 3 phenH. If the activation energy, Ea, is 126 kJ/mol and the rate constant at 30°C is 9.8 x 103 min 1, what is the rate constant at 35°C? O 4.5 x 10 min 1 O 4.4 x 10 min 1 O 2.3 x 10 min 1 O 2.2 x 10 min 1
The following initial rate data are for the reaction of hypochlorite ion with iodide ion in 1 M aqueous hydroxide solution: OCr +I- OI + CI Experiment [OCI"]o, M , M Initial Rate, Ms™ -1 1.70×10-3 1.70×10-3 3.40x10-3 3.40x10-3 4.57×10-3 9.15×10-3 4.57x10-3 9.15×103 1 5.41x10-4 1.08×10-3 1.08×10-3 2.17x10-3 2 3 4 Complete the rate law for this reaction in the box below. Use the form k[A]m[B]" , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n Rate = From these data, the rate constant is M's.
Kinetic data were obtained on the aqueous reaction of hydrogen peroxide with iodide ion and H+. H2O2(aq) + 3 l-(aq) + 2 H+(aq) → 13-(aq) + 2 H2O(1) Exp. 1 [H₂0₂], M 0.010 [I], M 0.010 [H+], M 0.00050 Initial Rate, M/s 1.15 x 10-6 2 0.020 0.010 0.00050 4.60 x 10-6 3 0.010 0.020 0.00050 1.15 x 10-6 4 0.010 0.010 0.00100 2.30 x 10-6 Determine the rate law for the reaction: none of the answers are correct R = 2.3 M-2 S-1 [H2O2]2 [H+] R = 1.15 x 10-2 M-1 S-1 [H2O2]2 R = 0.0115 M-1 S-1 [H2O2] [-]
Can you please solve question 12.46 and all of the sub problems and show the step by step to the solution
A reaction is performed to study the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: AsO 3³ +2 Ce4+ + H₂OAsO4³- + 2 Ce³+ +2 H+ The following reaction rate data was obtained in four separate experiments. Experiment 1 2 3 4 [AsO 3³¹10, M 3.80×10-2 7.60×10-2 3.80×10-2 7.60×10-2 [Ce4+]o, M 0.590 0.590 1.18 1.18 Initial Rate, Ms-1 6.64x10-3 1.33x10-2 2.66x10-2 5.31-10-2 The reaction is zero order with respect to water a) What is the order with respect to AsO3³- and Ce4+ b) What is the value of k (include units) *Show all your work.
Nitesh
The following initial rate data are for the reaction of hypochlorite ion with iodide ion in 1 M aqueous hydroxide solution:OCl- + I- OI- + Cl- Experiment [OCl-]o, M [I-]o, M Initial Rate, Ms-1 1 6.78×10-3 4.73×10-3 2.39×10-3 2 6.78×10-3 9.45×10-3 4.77×10-3 3 1.36×10-2 4.73×10-3 4.79×10-3 4 1.36×10-2 9.45×10-3 9.56×10-3 Complete the rate law for this reaction in the box below. Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n Rate = From these data, the rate constant is M-1s-1.