The following gas phase reaction was studied at 290 ° C, observing the change in pressure as a function of time, in a constant volume vessel: ClCO2CCl3(g) → 2COCl2(g) Determine the order of reaction, based on the following data: Time (s) P (mmHg) 0 15.76 181 18.88 513 22.79 1164 27.08

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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The following gas phase reaction was studied at 290 ° C, observing the change in pressure as a function of time, in a constant volume vessel:

ClCO2CCl3(g) → 2COCl2(g)

Determine the order of reaction, based on the following data:

Time (s)

P (mmHg)

0

15.76

181

18.88

513

22.79

1164

27.08

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