The gas phase decomposition of phosphine at 120 °C PH3(g)1/4 P4(g) + 3/2 H2(g) is first order in PH3. During one experiment it was found that when the initial concentration of PH3 was 6.02×10-2 M, the concentration of PHạ dropped to 8.61×10-³ M after 80 s had passed. Based on this experiment, the rate constant for the reaction is

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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The gas phase decomposition of phosphine at 120 °C
PH3(g)-
→1/4 P4(g) + 3/2 H2(g)
is first order in PH3.
During one experiment it was found that when the initial concentration of PH3 was 6.02×10-2 M, the concentration of PH3 dropped to 8.61×10-3 M after
80 s had passed.
Based on this experiment, the rate constant for the reaction is
Transcribed Image Text:The gas phase decomposition of phosphine at 120 °C PH3(g)- →1/4 P4(g) + 3/2 H2(g) is first order in PH3. During one experiment it was found that when the initial concentration of PH3 was 6.02×10-2 M, the concentration of PH3 dropped to 8.61×10-3 M after 80 s had passed. Based on this experiment, the rate constant for the reaction is
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