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The dehydrogenation of Methylcyclohexane (M) to produce Toluene (T) is conducted over a Pt/Al 2 O 3 catalyst using a differentially operated tubular reacto and is done in the presence of H 2 to prevent coke formation. It is asked to determine the kinetic parameters of the model for the empirical equation: a)-T₁ = k (PG) (P₂) b) and also by the mechanism below, considering, in this case, that P₁ = 1/3 PH2 (atm) M +0 → 0M Øμ→ OT + 3H₂ 0+ 0 + T H₂ + 0 → 0H₂ Experimental data for adjustment of kinetic parameters: Exp.rT PH2 PM (mol T / kgcat.s) (atm) (atm) 1 2 3 4 5 сл 6 7 1,2 1,25 1,3 1,1 0,92 0,64 1,27 8 1,28 9 1,25 10 1,30 1 1 1,5 1 0,5 1 0,5 0,5 1 0,5 0,1 3 1 0,25 34 3 4 2 1

The dehydrogenation of Methylcyclohexane (M) to produce Toluene (T) is conducted over a Pt/Al 2 O 3 catalyst using a differentially operated tubular reacto and is done in the presence of H 2 to prevent coke formation. It is asked to determine the kinetic parameters of the model for the empirical equation: a)-T₁ = k (PG) (P₂) b) and also by the mechanism below, considering, in this case, that P₁ = 1/3 PH2 (atm) M +0 → 0M Øμ→ OT + 3H₂ 0+ 0 + T H₂ + 0 → 0H₂ Experimental data for adjustment of kinetic parameters: Exp.rT PH2 PM (mol T / kgcat.s) (atm) (atm) 1 2 3 4 5 сл 6 7 1,2 1,25 1,3 1,1 0,92 0,64 1,27 8 1,28 9 1,25 10 1,30 1 1 1,5 1 0,5 1 0,5 0,5 1 0,5 0,1 3 1 0,25 34 3 4 2 1

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The dehydrogenation of Methylcyclohexane (M) to produce Toluene (T) is conducted over a Pt/Al 20 3 catalyst using a differentially operated tubular reactor, and is done in the presence of H 2 to prevent coke formation. It is asked to determine the kinetic parameters of the model for the empirical equation: a) - = k(P)) b) and also by the mechanism below, considering, in this case, that PT = 1/3 P H2 (atm) M + 0 → 0M OM- 07 + 3H2 87 + 0 +T H2 + 0 + 842 Experimental data for adjustment of kinetic parameters: Exp.rt PH2 PM (mol T/ kgcat.s) (atm)(atm) 1 1,2 2 1,25 1,5 1 3 1,3 0,5 1 4 1,1 0,5 0,5 0,92 1 0,25 6 0,64 0,5 0,1 7 1,27 3 8 1,28 1 4 9 1,25 3 10 1,30 4 1
Transcribed Image Text:The dehydrogenation of Methylcyclohexane (M) to produce Toluene (T) is conducted over a Pt/Al 20 3 catalyst using a differentially operated tubular reactor, and is done in the presence of H 2 to prevent coke formation. It is asked to determine the kinetic parameters of the model for the empirical equation: a) - = k(P)) b) and also by the mechanism below, considering, in this case, that PT = 1/3 P H2 (atm) M + 0 → 0M OM- 07 + 3H2 87 + 0 +T H2 + 0 + 842 Experimental data for adjustment of kinetic parameters: Exp.rt PH2 PM (mol T/ kgcat.s) (atm)(atm) 1 1,2 2 1,25 1,5 1 3 1,3 0,5 1 4 1,1 0,5 0,5 0,92 1 0,25 6 0,64 0,5 0,1 7 1,27 3 8 1,28 1 4 9 1,25 3 10 1,30 4 1
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