The complete combustion of salicylic acid releases 21.90 kJ of energy per gram of salicylic acid. In a particular bomb calorimeter (initially at room temperature), the combustion of 0.2342 g of salicylic acid, in the presence of excess oxygen, causes the temperature of the calorimeter to rise by 2.46 °C. When a 0.2446-g sample of an unknown organic substance is similarly burned in the same calorimeter, the temperature rises by 3.90 °C. What is the energy of combustion per unit mass of the unknown substance?
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
Constant Volume Calorimetry
The complete combustion of salicylic acid releases 21.90 kJ of energy per gram of salicylic acid. In a particular bomb calorimeter (initially at room temperature), the combustion of 0.2342 g of salicylic acid, in the presence of excess oxygen, causes the temperature of the calorimeter to rise by 2.46 °C. When a 0.2446-g sample of an unknown organic substance is similarly burned in the same calorimeter, the temperature rises by 3.90 °C. What is the energy of combustion per unit mass of the unknown substance?
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 2 images
