The combination of ozone, volatile hydrocarbons, nitrogen oxide, and surnlight in urban environments produces peranyacetylnitrate (PANI, a potent lachrymator. PAN decomposes to acetyl radicals and nitrogen diaxide in a process that is second order in PAN HO HO H-C-C-o-o- H-c-č-o-c H. 1st attempt See Periodic Table Part 1 The half-life of the reaction, at 38.00 °C and Pw 15.22 torr, is 186.89 hr. Calculate the rate constant for the reaction torr 'hr O See Hint Part 2 Determine the rate of the reaction at 38.00 C and Pr 15.22 torr torr/hr

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 30QAP
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The combination of ozone, volatile hydrocarbons, nitrogen oxide, and sunlight in urban environments produces peroxyacetylnitrate (PAN), a potent
lachrymator. PAN decomposes to acetyl radicals and nitrogen diaxide in a process that is second order in PAN:
HO
HO
H-C-C-o-o
H-c-ċ-o-
+]
H.
1st attempt
See Perlodic Table
Part 1
The half-life of the reaction, at 38.00 °C and Pow 15.22 torr, is 186.89 hr. Calculate the rate constant for the reaction.
torr 'hr
See Hint
Part 2
Determine the rate of the reaction at 38.00 C and Pra- 15.22 torr.
torr/hr
Transcribed Image Text:The combination of ozone, volatile hydrocarbons, nitrogen oxide, and sunlight in urban environments produces peroxyacetylnitrate (PAN), a potent lachrymator. PAN decomposes to acetyl radicals and nitrogen diaxide in a process that is second order in PAN: HO HO H-C-C-o-o H-c-ċ-o- +] H. 1st attempt See Perlodic Table Part 1 The half-life of the reaction, at 38.00 °C and Pow 15.22 torr, is 186.89 hr. Calculate the rate constant for the reaction. torr 'hr See Hint Part 2 Determine the rate of the reaction at 38.00 C and Pra- 15.22 torr. torr/hr
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