The below synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. compound a m compound b q Reagents HCI a. b. HBr C. H₂O, H₂SO4 d. Br₂ Cl₂ H₂, Pd Br₂, H₂O Cl₂, H₂O OsO4 then NaHSO3 Hg(OAc)2, H₂O then NaBH4 BH3 then H₂O₂, NaOH O3 then (CH3)2S e f. g. h. i. j. k. I. m. n. 0. p. q. r. 2 equivalents of NaNH₂ H₂, Lindlar's catalyst Na/NH3 H₂SO4, HgSO4 (sia)₂BH then H₂O₂, NaOH 1 equivalent of NaNH₂ compound c In this synthesis, reagents from the table (shown in blue) are used to carry out the indicated reactions. In the box below, draw the structure of compound b. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Consider E/Z stereochemistry of alkenes. • If more than one structure fits the description, draw them all. • If a compound is formed more than once, add another sketcher and draw it again. • If the reaction produces a racemic mixture, draw both stereoisomers. Separate structures with + signs from the drop-down menu.
The below synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. compound a m compound b q Reagents HCI a. b. HBr C. H₂O, H₂SO4 d. Br₂ Cl₂ H₂, Pd Br₂, H₂O Cl₂, H₂O OsO4 then NaHSO3 Hg(OAc)2, H₂O then NaBH4 BH3 then H₂O₂, NaOH O3 then (CH3)2S e f. g. h. i. j. k. I. m. n. 0. p. q. r. 2 equivalents of NaNH₂ H₂, Lindlar's catalyst Na/NH3 H₂SO4, HgSO4 (sia)₂BH then H₂O₂, NaOH 1 equivalent of NaNH₂ compound c In this synthesis, reagents from the table (shown in blue) are used to carry out the indicated reactions. In the box below, draw the structure of compound b. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Consider E/Z stereochemistry of alkenes. • If more than one structure fits the description, draw them all. • If a compound is formed more than once, add another sketcher and draw it again. • If the reaction produces a racemic mixture, draw both stereoisomers. Separate structures with + signs from the drop-down menu.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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