Be sure to answer all parts. Complete the reactions to show the synthesis of the following compound from (CH3)₂CHCH₂CH₂Br. Part 1: Part 2 out of 2 Br KOC(CH3)3 Br₂ H₂O view structure Base edit structure ... What reagent is needed where the "?" is located? Acid ~-↑

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%

HW 10 #12

Need help with the last part

**Synthesis of a Compound from (CH₃)₂CHCH₂CH₂Br**

**Objective:**
Complete the reactions to synthesize the following compound from (CH₃)₂CHCH₂CH₂Br (2-bromo-3-methylbutane).

![Target compound] : Cyclopropane structure with one carbonyl group attached.

---

**Part 1:**

**Reaction:**
A starting material represented by a straight-chain structure with a bromine (Br) substituent, undergoes a reaction with potassium tert-butoxide \((K^+ \; OC(CH₃)₃)\).

**Intermediate Compound:**
After this reaction, an alkene is formed, shown as having one double bond between the second and third carbon atoms in the chain.

*(View structure button provides visualization of the intermediate alkene.)*

---

**Part 2:**

**Reaction Mechanism:**

1. The alkene from Part 1 reacts with bromine (Br₂) in the presence of water (H₂O).
2. This produces a bromohydrin intermediate, which is integral in transitioning to the final product.

3. A reagent is needed in the next step (marked as "?") to transform this intermediate into the target epoxide compound.

**Appropriate Reagent:**
A base is required for the formation of the final compound.
- Selection: "Base" (indicated by a check mark).

---

**Conclusion:**
To synthesize the desired compound, employing a base as the reagent facilitates the reaction pathway, transforming the bromohydrin intermediate into the epoxide.
Transcribed Image Text:**Synthesis of a Compound from (CH₃)₂CHCH₂CH₂Br** **Objective:** Complete the reactions to synthesize the following compound from (CH₃)₂CHCH₂CH₂Br (2-bromo-3-methylbutane). ![Target compound] : Cyclopropane structure with one carbonyl group attached. --- **Part 1:** **Reaction:** A starting material represented by a straight-chain structure with a bromine (Br) substituent, undergoes a reaction with potassium tert-butoxide \((K^+ \; OC(CH₃)₃)\). **Intermediate Compound:** After this reaction, an alkene is formed, shown as having one double bond between the second and third carbon atoms in the chain. *(View structure button provides visualization of the intermediate alkene.)* --- **Part 2:** **Reaction Mechanism:** 1. The alkene from Part 1 reacts with bromine (Br₂) in the presence of water (H₂O). 2. This produces a bromohydrin intermediate, which is integral in transitioning to the final product. 3. A reagent is needed in the next step (marked as "?") to transform this intermediate into the target epoxide compound. **Appropriate Reagent:** A base is required for the formation of the final compound. - Selection: "Base" (indicated by a check mark). --- **Conclusion:** To synthesize the desired compound, employing a base as the reagent facilitates the reaction pathway, transforming the bromohydrin intermediate into the epoxide.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 1 images

Blurred answer
Knowledge Booster
Carboxylic Acids and their Derivatives
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY