TABLE 13-6 Standard Free Energies of Hydrolysis of Some Phosphorylated Compounds and Acetyl-CoA (a Thioester) AG" (kJ/mol) (kcal/mol) Phosphoenolpyruvate |1,3-Bisphosphoglycerate (- 3-phosphoglycerate + P;) -61.9 -14.8 -49.3 -11.8 Phosphocreatine ADP (→ AMP + P) -43.0 -10.3 -32.8 -7.8 ATP (- ADP + P;) -30.5 -7.3 ATP (+ AMP + PP) -45.6 -10.9 AMP (- adenosine + P;) -14.2 -3.4 PP, (- 2P) -19.2 -4.0 Glucose 3-phosphate -20.9 -5.0 |Fructose 6-phosphate Glucose 6-phosphate -15.9 -3.8 -13.8 -3.3 Glycerol 3-phosphate -9.2 -2.2 Acetyl-CoA -31.4 -7.5
TABLE 13-6 Standard Free Energies of Hydrolysis of Some Phosphorylated Compounds and Acetyl-CoA (a Thioester) AG" (kJ/mol) (kcal/mol) Phosphoenolpyruvate |1,3-Bisphosphoglycerate (- 3-phosphoglycerate + P;) -61.9 -14.8 -49.3 -11.8 Phosphocreatine ADP (→ AMP + P) -43.0 -10.3 -32.8 -7.8 ATP (- ADP + P;) -30.5 -7.3 ATP (+ AMP + PP) -45.6 -10.9 AMP (- adenosine + P;) -14.2 -3.4 PP, (- 2P) -19.2 -4.0 Glucose 3-phosphate -20.9 -5.0 |Fructose 6-phosphate Glucose 6-phosphate -15.9 -3.8 -13.8 -3.3 Glycerol 3-phosphate -9.2 -2.2 Acetyl-CoA -31.4 -7.5
Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
Section: Chapter Questions
Problem 1P
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Question
From data in Table 13-6, calculate the ΔG′° value for the following reactions:
(a) Phosphocreatine + ADP → creatine + ATP
(b) ATP + fructose → ADP + fructose 6-phosphate
Transcribed Image Text:TABLE 13-6 Standard Free Energies of
Hydrolysis of Some
Phosphorylated Compounds
and Acetyl-CoA (a Thioester)
AG"
(kJ/mol) (kcal/mol)
Phosphoenolpyruvate
|1,3-Bisphosphoglycerate
(- 3-phosphoglycerate + P;)
-61.9
-14.8
-49.3
-11.8
Phosphocreatine
ADP (→ AMP + P)
-43.0
-10.3
-32.8
-7.8
ATP (- ADP + P;)
-30.5
-7.3
ATP (+ AMP + PP)
-45.6
-10.9
AMP (- adenosine + P;)
-14.2
-3.4
PP, (- 2P)
-19.2
-4.0
Glucose 3-phosphate
-20.9
-5.0
|Fructose 6-phosphate
Glucose 6-phosphate
-15.9
-3.8
-13.8
-3.3
Glycerol 3-phosphate
-9.2
-2.2
Acetyl-CoA
-31.4
-7.5
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