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Synthesize (Z)-hept-5-en-2-one from ethyl acetoacetate (CH3COCH₂CO₂Et) and the given starting material. Br (z)-hept-5-en-2-one Draw four organic reaction intermediates, and select the single best set of reagents for each of the six reaction steps. CH3COCH₂CO₂Et draw structure ... draw structure ... O [1] NaOEt, [2] HC=CCH₂Br [1] HCI, [2] HC=CCH₂Br [1] Mg, [2] HC=CCH₂Br [1] H₂O, Cl₂, [2] HC=CCH₂Br 0000 O O H₂SO4 OH₂0¹, A OOO OOOO H₂ (2 equiv), Pd-C OOOO mCPBA HOCH2CH2OH, TSOH [1] LDA, THF; [2] BrCH₂CH₂Br OLIAIH4 KMnO4, H₂O, HO™ [1] NaH; [2] CH ₂1 H₂O, Br₂ H₂O, NaOH KMnO4, H₂O, HO™

Synthesize (Z)-hept-5-en-2-one from ethyl acetoacetate (CH3COCH₂CO₂Et) and the given starting material. Br (z)-hept-5-en-2-one Draw four organic reaction intermediates, and select the single best set of reagents for each of the six reaction steps. CH3COCH₂CO₂Et draw structure ... draw structure ... O [1] NaOEt, [2] HC=CCH₂Br [1] HCI, [2] HC=CCH₂Br [1] Mg, [2] HC=CCH₂Br [1] H₂O, Cl₂, [2] HC=CCH₂Br 0000 O O H₂SO4 OH₂0¹, A OOO OOOO H₂ (2 equiv), Pd-C OOOO mCPBA HOCH2CH2OH, TSOH [1] LDA, THF; [2] BrCH₂CH₂Br OLIAIH4 KMnO4, H₂O, HO™ [1] NaH; [2] CH ₂1 H₂O, Br₂ H₂O, NaOH KMnO4, H₂O, HO™

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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HW9 #14

Be sure to answer all parts. Synthesize material. (Z)-hept-5-en-2-one from ethyl acetoacetate (CH3COCH₂CO₂Et) and the given starting Br CH3COCH₂CO₂Et Draw four organic reaction intermediates, and select the single best set of reagents for each of the six reaction steps. draw structure ... draw structure ... O O O OOOO لد OOOO (z)-hept-5-en-2-one H₂SO4 OH30¹, A O O O O [1] NaOEt, [2] HC=CCH₂Br [1] HCI, [2] HC=CCH₂Br [1] Mg, [2] HC=CCH₂Br [1] H₂O, Cl₂, [2] HC=CCH₂Br H₂ (2 equiv), Pd-C mCPBA HOCH₂CH₂OH, TSOH [1] LDA, THF; [2] BrCH₂CH₂Br OLIAIH4 OKMnO4, H₂O, HO™ [1] NaH; [2] CH₂I H₂O, Br₂ H₂O, NaOH KMnO4, H₂O, HO™
Transcribed Image Text:Be sure to answer all parts. Synthesize material. (Z)-hept-5-en-2-one from ethyl acetoacetate (CH3COCH₂CO₂Et) and the given starting Br CH3COCH₂CO₂Et Draw four organic reaction intermediates, and select the single best set of reagents for each of the six reaction steps. draw structure ... draw structure ... O O O OOOO لد OOOO (z)-hept-5-en-2-one H₂SO4 OH30¹, A O O O O [1] NaOEt, [2] HC=CCH₂Br [1] HCI, [2] HC=CCH₂Br [1] Mg, [2] HC=CCH₂Br [1] H₂O, Cl₂, [2] HC=CCH₂Br H₂ (2 equiv), Pd-C mCPBA HOCH₂CH₂OH, TSOH [1] LDA, THF; [2] BrCH₂CH₂Br OLIAIH4 OKMnO4, H₂O, HO™ [1] NaH; [2] CH₂I H₂O, Br₂ H₂O, NaOH KMnO4, H₂O, HO™
I I I draw structure... draw structure... H₂, Lindlar catalyst NaBH4 Na or Li, NH3 H₂, Pd-C H3O+ HO™ H₂O NaBH4
Transcribed Image Text:I I I draw structure... draw structure... H₂, Lindlar catalyst NaBH4 Na or Li, NH3 H₂, Pd-C H3O+ HO™ H₂O NaBH4
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