Synthesize (Z)-hept-5-en-2-one from ethyl acetoacetate (CH3COCH2CO₂Et) and the given starting material. Br Upload Choose a File (z)-hept-5-en-2-one
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- The main product of the reduction of 3-ethyl-2-pentanone, in the presence of LIAIH4 as catalyst, is: bv) CH–CH2CH CHI CHO CH-CH₂ cx) CH-CH₂-CH-0-CH3 1 CH₂ CH3 VALAISUU, US OH KHI CHICH, CHÍCH CHO CH-CH3 Ik) CH,CH, CH, CH, COO CHI CHDraw the major organic product(s) for the following reactions, including stereochemistry when appropriateMyo-inositol, the most prominent naturally occurring form of inositols, is a carbocyclic polyol that plays an important role as the structural basis for a number of secondary messengers in eukaryotic cells. It is generated in vivo from the aldol cyclization of glucose-6-phosphate to myo-inositol-1-phosphate
- Provide the structure of the product(s) with stereochemisty if appropriate. If multiple products indicate major product or if products are formed in equal amounts. If there is no reaction expected explain why. (a) OH HIO4 (the protecting group is remained) CHO H HOH2C OH (b) CHO -ОН NaCN # HO -H H -OH CH₂OH (c) CHO HO- -H HO -H NH₂OH 張一 H -OH H -OH CH₂OH i) Ba(OH)2 ii) MeOH, H₂SO4 NaOAc Ac₂0 NaOMe MeOHDevise a synthesis of (E)-1-phenylhex-1-ene (CH3CH2CH2CH2CH = CHPh) using hydrocarbons having ≤ 6 C’s and a Suzuki reaction as one of the steps.Capsaicin, the spicy component of hot peppers, can be prepared from amine X and acid chloride Y. Devise a synthesis of Y from (E)-6-methylhept-4-en-1-ol [(CH3)2CHCH=CH(CH2)3OH], CH2(CO2Et)2, and any required inorganic reagents.
- Draw a structural formula for the ketal formed when two molecules of ethanol combine with one cyclohexanone molecule. You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. opy aste ChemDoodleGive the structures of A to E, showing the absolute stereochemistry in each case.Both OH groups of the β,β-diol react with excess ethyl chloroformate, but only one OH group of the b,a-diol reacts under the same conditions.Explain the difference in reactivity.
- Devise a synthesis of the ketone hexan-3-one, CH3CH2COCH2CH2CH3, from CH3CH2Br as the only organic starting material; that is, all the carbon atoms in hexan-3-one must come from CH3CH2Br. You may use any other neededreagents.G.260.Ignoring stereoisomers, draw the two possible enols for butan-2-one (CH3COCH2CH3), and predict which one is more stable.