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What changes can be made to the hydrogenation reaction to make it safer for beginner students?
![Step 2 -Transfer Hydrogenation of Dehydrozingerone
HO
Н
+
Na
H2SO4
Pd/Alumina (Cat)
Methanol
HO](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc4436f5f-01e3-4d46-baa5-3f23cf388ae7%2Ffeef6794-76b9-42ef-a446-192ee40878b7%2Fofuqz0n_processed.jpeg&w=3840&q=75)
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- + OH HO + !!!10 HO HOLI > OsO4 (catalytic) NMOP17A.1 The following initial-rate data were obtained on the rate of binding of glucose with the enzyme hexokinase present at 1.34 mmol dm. What is (a) the order of reaction with respect to glucose, (b) the rate constant? [C,H,„O,J/(mmoldm³) 1.00 1.54 3.12 4.02 12 v/(mol dms) 5.0 7.6 15.5 20.0요스아 of N ①Na ②~ Br & Dyona Тон e OHOCO Nat Br нео CH3I На •Had
- None4. The hydrogenation of acetylene (C2H2) on Pd metal sites (*) is proposed to occur via elementary steps consisting of: 1) QE dissociative adsorption of H2; 2) QE molecular adsorption of C2H2; 3) & 4) QE sequential addition of H* to form C2H4*; 5) Ireversible desorption of ethylene. (a) Write the mechanism of the reaction with the stoichiometric number of each step. (b) Derive the rate expression in tems of constants and measurable quantities when CH,* and * are the MARI. If C;H4 is in the MARI expression, why is the rate independent of the concentration of C¿H4 in the gas phase? (c) At some conditions, the experimental rate is zero order in both CH2 and H2. What additional assumption(s) are required for this observation to be consistent with the rate expression derived in part (b)? If, under certain experimental conditions, an effective zero order rate constant is measured, explain the chemical significance of this constant (in terms of rate or equilibrium constants for elementary…Methyl acetate (CH;COOCH3) is formed by the reaction of acetic acid with methyl alcohol. If the methyl alcohol is labeled with oxygen-18, the oxygen-18 ends up in the methyl acetate: CH;COH + HSOCH3 CH;Č18OCH3 + H,O (a) Do the C-OH bond of the acid and the O-H bond of the alcohol break in the reaction, or do the O-H bond of the acid and the C-OH bond of the alcohol break? (b) Imagine a similar experiment using the radioisotope H, which is called tritium and is usually denoted T. Would the reaction between CH;COOH and TOCH; provide the same information about which bond is broken as does the above experiment with Hl$OCH;?
- savvasrealize.com (M-F)-23-24 rk 3-D Assessment 1: Storylines 1 and 2 DUE Jun 1-1 In the lab, you conduct two experiments. For your first experiment, you are breaking down cane sugar (sucrose) into simpler compounds by boiling it. You write this equation: C12H22O11 A+B (breakdown) For your second experiment, you are determining suitable reagents for the complete oxidation of ethanol. You write this equation: C2H5OH C (oxidation) Periodic Table From your experiments, you found that A, B, and C share the same empirical formula. C has a different molar mass than A. Will A and C show the same chemical behavior? Explain. Χ Χ Ω ΧΟ BIV Progress C Desk 2 @ 12 -> #3 C $ 54 W e r % 95 DELL 66 Δ 0 7 29 & t y u 8 ** Question 28 of 40 Bad 0. 61 ) Jun 0 O P1. Which breaks down more quickly in an aqueous solution? DNA RNAThank you
- Q5:- A:-Consider the following monomers and initiating systems:- Monomers Initiating Systems CH,COOH + Fe" vinyl chloride AICI, + (CH),CCI acrylic acid Li + NH, 1- What is the actual initiating species that initiates polymerization for each of the vinyl alcohol initiating systems? 2- Show the mechanism polymerization for each it?The acid-catalyzed hydrolysis of sucrose, C12H22O11 + H₂O + H+ -> C6H12O6 + C6H12O6 + H+ is known as "inversion of sucrose" because the angle, a, by which the solution rotates polarized light changes from positive to negative as the reaction proceeds (data from 30 degree C): t/hr a 0 78 2 71 4 12 18 24 42 65.10 44.60 32.40 22.45 2.30 48 -1.96 61 -9 86 95 -15.80 -17.25 -21.15 ∞ Use this data to show that the reaction is first order and determine its rate coefficient (at 30 degree C).P17A.1 The following initial-rate data were obtained on the rate of binding of glucose with the enzyme hexokinase present at 1.34 mmol dm. What is (a) the order of reaction with respect to glucose, (b) the rate constant? C,HO/(mmoldm) 1.00 1.54 3.12 4.02 v/(mol dms) 7.6 20.0 5.0 15.5
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