Step 2 -Transfer Hydrogenation of Dehydrozingerone HO Н + Na H2SO4 Pd/Alumina (Cat) Methanol HO Step 1- The Synthesis of Dehydrozingerone from Vanillin Step 1 HO Vanillin H + KOH Acetone/H₂O Reflux ALDOL CONDENSATION HO fre Dehydrozingero ne (Vanillid enea ce to ne)

Step 2 -Transfer Hydrogenation of Dehydrozingerone HO Н + Na H2SO4 Pd/Alumina (Cat) Methanol HO Step 1- The Synthesis of Dehydrozingerone from Vanillin Step 1 HO Vanillin H + KOH Acetone/H₂O Reflux ALDOL CONDENSATION HO fre Dehydrozingero ne (Vanillid enea ce to ne)

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution

Section16.SE: Something Extra

Problem 60AP

See similar textbooks

Related questions

Q: a) Which of the following chemical species could have their electronic ground state energy and…

A: To identify whether the given system can be analyzed using the Restricted Hatree Fock method, we…

Q: 9. Give the final product a) 1) Me Ms Br. 23420 3) conc. H2504, heat b) ك

A: Step 1: Step 2: Step 3: Step 4:

Q: Consider the following reaction at 298K. → Hg (I) + Fe2+ (aq) Hg2+ (aq) + Fe (s) → Which of the…

A: Step 1:Standard reduction potential values areHg2+ (aq) + 2e- = Hg (l) ; E0Hg2+/Hg(l) = 0.855 VFe2+…

Q: For the reaction NO2(g) + NO(g) N2O(g) + O2(g) K=0.914. Equal amounts of NO and NO2 are to be placed…

A: Given: V=5.00L;@ Equilibrium: [N2O]=0.0616MNO2(g)+NO(g)⇌N2O(g)+O2(g)Kc=0.914Step 1: Define…

Q: write a mechanism for the following ееее ΟΗ HO он оно H3O+, H₂O H3O+, H₂O Он ὋΗ ὋΗ OH H3O+, H₂O Δ

A: Step 1: Step 2: Step 3: Step 4:

Q: None

A: Step 1:Step 2:Step 3:

Q: 3. Beginning with the indicated starting materials (plus another starting material of your choice…

Q: (SYN) Show how to synthesize each of these alcohols from a ketone or aldehyde that has the same…

Q: Name the given compound. Make sure you include the appropriate configuration for each of the chiral…

A: In the structure, the parent chain is the cyclopentane.Next, it has a substituent that has 8 as the…

Q: Provide a brief explanation of one specific application on High Performance Liquid Chromatography…

A: High Performance Liquid Chromatography (HPLC) can be used in monitoring the safety and efficacy of…

Q: (c) According to Le Chatelier's principle, what conditions of (i) Temperature and (ii) pressure…

A: Effect of Changing the Temperature According to Le Chatelier's Principle: To predict the direction…

Q: Use bond energies to calculate the heat of reaction: :ɑ—C:+ H—H Round your answer to 3 significant…

A: Step 1: We know that, Heat of reaction can be calculated by using formula as ΔH = ∆H (bond broken)…

Q: IV = II Use the letter (a-k) in the box provided for the reagent required for the each of the given…

Q: 7) The correct structure that corresponds to the spectroscopic data given below is [IR 2720, 1710 1…

A: compound contains aldehydic group not carboxylic group as HNMR shows peak at 9.8 ppm which is region…

Q: The weak acid hydrofluoric acid, HF, and the strong base lithium hydroxide react to form the salt…

Q: None

A: Step 1: A Comprehensive Description of the Amine Basicity Order:The ability of the nitrogen atom to…

Q: Nitric oxide (NO) reacts with H2 to form N2O and H2O. It is known that there are two elementarysteps…

A: The rate law tells us which is the rate determining step.The slowest step is the rate determining…

Q: = O Kinetics and Equilibrium 2/5 Bi Calculating an equilibrium constant from a heterogeneous…

A: Given: V=8.3Lmass,gMolarmass,g/mol2Hg(l)7.2200.59+O2(g)15.432.00→2HgO(s)11.7216.59Step 1:…

Q: Predict the major product formed when the compounds shown below react with each other under the…

A: Step 1:Given reaction in known as Diels-Alder reaction.The Diels-Alder reaction involves a diene and…

Q: Question 7 Which of these coenzymes is required for the following reaction? NH3 HS A.…

A: The reaction shown in the image is a transformation of a thiol group (-SH) into a thiol ester,…

Q: Show how you would perform the following synthesis, describing each step.

A: Step 1: Step 2: Step 3: Step 4:

Q: Be sure to answer all parts. Enter your answers in scientific notation. At a particular temperature,…

A: Part A:Part B:

Q: Upp solve all

A: 1. To determine the relative uncertainty of the solution, we need to calculate the relative…

Q: Н. Н. OH NaOH Δ Н Н. NaOH Δ Н. H Н. Aldol:

A: Step 1: Aldol Condensation :Two molecules of an aldehyde or a ketone, containing at least one…

Q: Draw a triacylglycerol (triglyceride) made from glycerol, myristic acid [CH3(CH2) 12COOH], palmitic…

A: Step 1: Step 2:

Q: 14. Oral solutions of Lipitor are often prepared in a buffer solution with a pH = 7.4. Which of the…

A: Step 1: To choose the best buffer pair for preparing a solution with a pH of 7.4, you need to…

Q: how to synthesize this?

A: 1. First, we need to halogenate the alpha carbon (the carbon, adjacent to the carbonyl carbon)We…

Q: 1) Draw the products of the following reactions. Draw stereoisomers and identify them as…

Q: please give Step by Step Solution otherwise i give you DISLIKE !

A: Step 1:Nucleophilic attack by phenyl magnesium bromide (grignard reagent) to the carbonyl carbon of…

Q: Determine whether the following will proceed via SN1, SN2, E1 or E2 reaction. Draw the major…

A: The above reaction is a SN2 reaction .it cannot be a SN1 reaction because according to BREDTS rule…

Q: 4. Allene, C3H4, has point group symmetry Dzd, with character table provided below. It can be…

A: Step 1: Step 2:Step 3:

Q: For a and b, arrange the following in increasing rate of reaction with HCl

A: Thank you.

Q: 7. Use the table of standard cell potentials to find AG° and calculate Kea for the following…

A: 7a. Given: T=298.15KAg(aq)++Fe(aq)2+→Ag(s)+Fe(aq)3+Step 1: Write the equations we need to…

Q: Use the table of indicators below to choose the most appropriate indicator to use when titrating…

Q: Show work, thank you!

Q: given both answer

A: 1. The angular momentum quantum number, signified by l, describes the general shape or region an…

Q: One of the triggering condition for a fusion of Coronovirus (COVID-19) with a human cell is an…

A: The inability to effectively dispose of CO2 from the bloodstream, referred to as respiration…

Q: Question 15 of 18 What is S° for A in the reaction 4 A→ 3 B if AS°(rxn) =-164.4 J/mol ⚫ K? [S° (B) =…

A: Entropy of reaction can be determined by following the formula below.∆S˚rxn = Σnp∆S˚ (products) -…

Q: DO NOT upload images of handwritten or typed solutions.

Q: 17. What is the Aldol addition product formed from reaction of the following compound with itself? О…

Q: Figure out and explain what the reagents would be used in this reaction and show/draw the mechanism…

A: In first step it is aldol condensation reaction. Proton is abstracted by base and then attack on…

Q: please answer in text form and in proper format answer with must explanation , calculation for each…

Q: Choose the best reagents for the following reaction. B is the wrong answer.

A: Thank you.

Q: involve titrating a 100.0 mL sample of 0.20 M HF is titrated with 0.10 M KOH. The Ka of HF is 3.5 ×…

A: Step 1: Calculate the initial moles of acid and base added in the mixture/solution. Moles of HF =…

Q: None

A: Among the carbonyl compounds the acidity is determined by the reactivity of the carbonyl compounds.…

Q: A titration was performed using a 25.00 mL sample of 0.15 M weak acid and 0.092 M strong base. What…

A: Step 1: To determine the pH after the equivalence, point in a titration of a weak acid with a strong…

Q: Find the rate law constant and the order of the reaction a and b K[H2O]a[I-]b Concentrations:…

A: The rate equation shows how the rate of the reaction changes with a change in the concentration of…

Q: None

A: Here's how we achieved the balanced equation: Identify the oxidation and reduction…

Q: Describe Auger/screw mechanisms and dosator mechanism by which capsules are produced. Use diagrams…

A: Auger/Screw Mechanisms:The auger or screw rotates at a controlled speed to draw the powder or…

Q: Show steps how to get the amount of error (Pduration - Pmarket) for second question in the picture,…

A: Answer to 9b-20:b. -$0.75Here's why:Duration: We don't need the exact duration value for this…

Question

List the uses of Dehydrozingerone and Zingerone made in the attached reaction. (Be specific: If its a flavor or fragrance describe its smell; if it has medicinal uses list what conditions it can be used to treat etc..)

Step 2 -Transfer Hydrogenation of Dehydrozingerone
HO
Н
+
Na
H2SO4
Pd/Alumina (Cat)
Methanol
HO

Step 1- The Synthesis of Dehydrozingerone from Vanillin
Step 1
HO
Vanillin
H
+
KOH
Acetone/H₂O
Reflux
ALDOL CONDENSATION
HO
fre
Dehydrozingero ne
(Vanillid enea ce to ne)

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step by step

Solved in 2 steps

SEE SOLUTION Check out a sample Q&A here

Similar questions

Fluvastatin, a cholesterol-lowering drug, can be prepared by thefollowing three-step reaction sequence. Identify intermediates A and Band the final product, fluvastatin.
Synthesize the compund (Amlodipine) via Hantzsch dihydropyridine synthesis.
With sulfides are treated with α,β-unsaturated ketones and aldehydes, they can attackeither through direct or conjugate addition. Based on the NMR spectrum obtained fromthe product of the reaction below, indicate whether the reaction occurs by direct orconjugate addition and provide an arrow pushing mechanism
OH - NH, Br2/KOH →product; 1. (a-hydroxy amide) Product of this Hoffmann bromamide reaction is : OH (a) Ph – Ĉ-CH3 (Ъ) Ph — CHO (c) Ph- CH3 (d) Ph – CH2 -NH2 NO2
Indicate the product of Nucleophilic Substitution and Elimination of the following reactions(Note: draw proper settings when needed)
(c) With reference to the following reaction scheme: Met N Me Boc 20 OMe DIBAL, toluene, -78 °C then H₂O w/up Me+N Mé Boc 21 H Useful structure: DIBAL= H₂ Al Y Bary (i) Provide a curved arrow mechanism for the reduction of ester 20 to aldehyde 21. (ii) Explain why the reduction of ester 20 selectively affords aldehyde 21 in the presence of DIBAL, whereas treatment of 20 with LiAlH4 leads to over-reduction.
Can you please draw out a complete curve arrow mechanism with the reagent and intermediate steps?
which of the following is the correct mechanism for the acid-catalyzed conversion of a keto to enol isomer? A B C D :: :O: H+ H+ 一 :0: In :ÖH :: :ÖH 另一面一卡一工.. H + H H H H H+ :ÖH 犬一一次。 H+ :ÖH 加一一 H+ :ÖH :0 :ÖH H+ :ÖH
Synthesize 48 assume that the followine also aveilable are acetoacetic ester malonic cstes NHCH3
Which of the following strategies is NOT expected to effect the reduction of 4-tert-butanol to tert-butylcyclohexane. Reaction conditions O LIAIH4, THF O NH2NH2, KOH O Zn(Hg), HCI O HSCH2CH2SH, H*; ) H2, Raney Ni°
Rank the following compounds from MOST react Mucieophilic acyl substitution. Enter the number 1 in the and number 3 in the box under the least reactive compou om bajada! 517 om oonuod O ofque ex Explain why 1 is more reactive compared to 2
A molecule of propanone reacts with an cyclohexylethanone in presence of aq. NaOH to combine together, and the resulting product is boiled to produce another product, (i) CH3 -NH2 НО H;CO