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- For the compounds shown, use the R/S configuration given in the compound name to finish drawing the structure by changing bonds to the the appropriate wedge‑and‑dash bonds. For each compound, change two of the in‑plane bonds to a wedge and a dashed bond. You can select the chiral bond and click on top of an in‑plane bond to quickly modify it.Which objects are asymmetric (have no plane of symmetry): (a) a circular clock face; (b) a football; (c) a dime; (d) a brick; (e) a hammer; (f) a spring?A chiral center is a(n) (select all possible answers) atom bearing groups such that interchanging of any two groups leads to a stereoisomer. non‑superimposable mirror image. tetrahedral atom bonded to 4 different substituents. plane of symmetry so that there are no stereoisomers. enantiomer. tetrahedral atom.
- H ÇI CH3-C-COOH он CH3-C-CH2Br 1. ČI a b 81. Consider the structures above. Which of these two contains a stereocenter? Draw thestructure on your answer sheet and mark the stereocenter with an asterisk. 82. Which of these two is a chiral molecule? Explain your answer. 83. Which of these two can exist as a pair of enantiomers? 84. Draw the pair of enantiomers using three-dimensional representation.what are all the chiral carbons in the picture?4 PART QUESTION. PART 1: The last unique stereoisomer is? PART 2: Which of these structures are enantiomers? PART 3: Which of these structures are diastereomers? PART 4:
- Draw all stable isomers of C4H9Cl. Be sure to label cis/trans isomers on rings, Z/E isomers on double bonds as well as R/S on chiral centers.For example, alanine is a chiral amino acid that has two enantiomers: (+)-alanine and (-)-alanine. These two are optical isomers. NH2 NH2 4. One of the most important properties of chiral molecules in solution is their effect on plane- polarized light, this effect is called optical activity. -C H 2 COOH HOOC CH When an enantiomer rotates a plane-polarized light in the positive direction or clockwise, it is dextrorotary (+ or d), while for a negative direction or counterclockwise, it is levorotary (- or l) (+)-Alanine (-)-Alanine Alanine is a chiral amino acid that has two enantiomers: (+)-alanine and ()-alanine. These two are optical isomers.Consider vitamin C, shown below. It contains [1,2,3,or4] chiral carbon atoms and the carbon atom indicates by an arrow has a [linear, trifocals pyramidal, trifocals planar, or tetrahedral] shape.
- 4. Draw the R.R configuration of the following chiral molecule (use the skeleton provided and put groups were they need to go). CHÍCH CH(OH)CH(NH,CH1. How many chiral carbon atoms are in the following compound? CHCIBRCH2CHBRCH3 a) 0 b) 1 c) 2 d) 3 4. Which of the following compounds will not show optical activity? a) CH2CICHBRCI b) CH;CH(OH)CH3 c) CH;CH2CHĆICH3 d) CH2(OH)CH(NH2)COOH 2. How many chiral carbon atoms are in the following compound? 5. Three of the following projection formulas are the same compound. The other is the enantiomer. Which is the enantiomer? CH2(OH)CH(OH)CH(OH)CH(OH)CH2OH CH,OH c=0 a) 1 b) 2 c) 3 d) 4 ОН Н H-C=0 a) НО -H 3. The maximum number of ČHHOH stereoisomers theoretically possible for the compound below is: b) H-C =0 -CH2OH CH2(OH)CH(OH)CH(OH)CH(OH)CHO c) CH2OH a) 8 b) 6 c) 16 d) 4 H. - OH d) H-C=0A tetrahedral carbon atom will be chiral if it has four ______ groups attached to it Fill in the blank