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State the Franck Condon Principle and, with the aid of diagrams, explain how electronic transitions dictate the vibrational fine structure/band shape of electronic transitions. (a) Explain, what is meant by the following terms in IR spectroscopy: fundamental mode, combination band and Fermi resonance. (b) From the vibrational spectrum of CO, we was determined as 2169.23 cm¹¹, Xe as 0.06. Calculate Vmax and estimate the bond dissociation energy. De for this molecule.

State the Franck Condon Principle and, with the aid of diagrams, explain how electronic transitions dictate the vibrational fine structure/band shape of electronic transitions. (a) Explain, what is meant by the following terms in IR spectroscopy: fundamental mode, combination band and Fermi resonance. (b) From the vibrational spectrum of CO, we was determined as 2169.23 cm¹¹, Xe as 0.06. Calculate Vmax and estimate the bond dissociation energy. De for this molecule.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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State the Franck Condon Principle and, with the aid of diagrams, explain how electronic transitions dictate the vibrational fine structure/band shape of electronic transitions. (a) Explain, what is meant by the following terms in IR spectroscopy: fundamental mode, combination band and Fermi resonance. (b) From the vibrational spectrum of CO, was determined as 2169.23 cm¹¹, Xe as 0.06. Calculate Vmax and estimate the bond dissociation energy. De for this molecule.
Transcribed Image Text:State the Franck Condon Principle and, with the aid of diagrams, explain how electronic transitions dictate the vibrational fine structure/band shape of electronic transitions. (a) Explain, what is meant by the following terms in IR spectroscopy: fundamental mode, combination band and Fermi resonance. (b) From the vibrational spectrum of CO, was determined as 2169.23 cm¹¹, Xe as 0.06. Calculate Vmax and estimate the bond dissociation energy. De for this molecule.
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