Select all the following statements that are correct.1BrBr2Br34BrCompound 1 will react faster than Compound 3 in the Nal/2-butanone reactivitytest.Compound 1 will be the fastest to react with Nal/2-butanone because it is aprimary alkyl halide.Compound 4 will be the fastest to react with Nal/2-butanone because it is ahighly substituted alkyl halide.Compound 2 will be the fastest to react with Nal/2-butanone because it is atertiary alkyl halide.Compound 2 will react faster than Compound 3 in the Nal/2-butanone reactivitytest.

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Answered: Select all the following statements…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter21: Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions

Section21.SE: Something Extra

Problem 54AP: The following reactivity order has been found for the saponification of alkyl acetates by aqueous...

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The following reactivity order has been found for the saponification of alkyl acetates by aqueous NaOH. Explain. CH3CO2CH3 > CH3CO2CH2CH3 > CH3CO2CH(CH3)2 > CH3CO2C(CH3)3
Write the products of the following sequences of reactions. Refer to your reaction roadmaps to see how the combined reactions allow you to navigate between the different functional groups. Note that you will need your old Chapters 611, Chapters 1518, and Chapter 19 roadmaps along with your new Chapter 20 reaction roadmap for these.
How would you synthesize the following compounds from cyclohexanone using reagents from the table? Use letters from the table to list reagents in the order used (first at the left). Reagents a 1. CH3MgBr/dry ether 2 H3O+ e 1. OsO4 i 1. BH3/THF 2. NaHSO3/H2O 2. H₂O₂ / NaOH b 1. C6H5MgBr / dry ether f 1. NaBH4 j Mg / dry ether 2 H3O+ 2. H3O+ с PBr3 g HOCH2CH2OH/HCI k H2/Pd d m-chloroperbenzoic h H3O+ / heat I CrO3 / H3O+ acid m cyclohexanone a) cyclohexylbenzene b) 2-phenylcyclohexanone Submit Answer Try Another Version 3 item attempts remaining
How would you synthesize the following compounds from cyclohexanone using reagents from the table? Use letters from the table to list reagents in the order used (first at the left). Reagents a 1. CH3MgBr / dry ether 2 H3O+ e 1. OsO4 i 1. BH3/THF 2. NaHSO3/H₂O 2. H₂O₂ / NaOH b 1. C6H5 MgBr / dry ether f 1. NaBH4 j Mg / dry ether 2 H3O+ 2. H3O+ C PBг3 g HOCH2CH2OH/HCI k H2/Pd d m-chloroperbenzoic h H3O+ / heat 1 CrO3 / H3O+ acid a) 2-phenylcyclohexanone b) cyclohexylbenzene m cyclohexanone
Rationalize the selectivity observed in the benzil reduction. Draw the transition states of the nucleophilic attack leading to either meso or racemic products and indicate why one is more stable than the other.
Question 13 Propose best Williamson ether syntheses for the following compounds. Select all applicable options (multiple answers can be possible). Note: Some compounds cannot be made using Williamson synthesis reaction. ΚΗ A: + ⚫OH ΕΘ OK SN2 KH ΘΘ + -Br B: -OH OK SN1 C: ☐ A B ☐ C Cannot be synthesized using Williamson ether syntheses.
Question 11 Propose best Williamson ether syntheses for the following compounds. Select all applicable options (multiple answers can be possible). Note: Some compounds cannot be made using Williamson synthesis reaction. A: Хон OH ΚΗ مر OK Br SN2 KH B: OH OK SN1 C: Α ABC ☐ C 1000 Br Cannot be synthesized using Williamson ether syntheses.
From the lists of available reagents select the one(s) you would use to in a preparation of acetophenone (phenyl methyl ketone) from toluene. (In no case are more than three steps necessary.) Reagents Available d. CH3CHO e. Hg(OAc)2, H₂O; then NaBH4 a. CH3COCI, AICI 3 b. (CH3)2CuLi c. CH3MgBr, then H3O* f. KMnO4, H₂O List reagents by letter in the order that they are used; example: fa. Reagents used: Try Another Version g. Mg h. NaOH, H₂O i. Dess-Martin periodinane 10 item attempts remaining j. SOCI₂
Question 14 Propose best Williamson ether syntheses for the following compounds. Select all applicable options (multiple answers can be possible). Note: Some compounds cannot be made using Williamson synthesis reaction. Br ΚΗ A: LOH 00 OK SN2 Br NaH 00 B: OH ONa SN2 C: Cannot be synthesized using Williamson ether syntheses. □ A B C
Be sure to answer all parts. An allylic alcohol contains an OH group on a carbon atom adjacent to a C-C double bond. Treatment of allylic alcohol A with HCl forms a mixture of two alllylic chlorides, B and C. Select a stepwise mechanism that illustrates how both products are formed. CI HCI + H20 HO. CI A B Part 1 out of 4 Select the correct first step. :Cl: он :Cl: HO. HO. :Cl: HO. HO. :Ci: :CI: HO. Next part
Which of the following is the product in this Grignard reaction? ОН O 1) O 2) ОН 4) H.
From the table of available reagents select the one(s) you would use to convert cyclohexanone to the following compound: CH,CH,CO,H Use the minimum number of steps; from one to five are required. List reagents by letter in the order that they are used; example: fa. Reagents Available a. BH3, THF; followed by H₂O₂, OH b. Br₂, CH3CO₂H c. HCN, KCN d. H3O*, heat e. LDA (lithium diisopropylamide) f. NaBH4 g. Na* -CH(CO₂C₂H5) (from CH₂(CO₂C₂H5)2 + Na* -OC₂H5) h. PBr3 i. PhCH₂Br j. Ph3P+--CH₂ k. pyridine, heat I. PhBr

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