SAIC Pr7.1 The compound Na,lrCl, reacts with triphenylphosphine in diethyleneglycol in an atmosphere of CO to give trans-[IrCI(CO)(PPH3)], known as "Vaska's compound'. Excess Co gives a five coordinated species and treatment with NaBH in ethanol gives [IrH(CO)2 (PPH3)2]. Derive a formal name for 'Vaska's compound'. Draw and name all isomers of the two five-coordinate complexes.

SAIC Pr7.1 The compound Na,lrCl, reacts with triphenylphosphine in diethyleneglycol in an atmosphere of CO to give trans-[IrCI(CO)(PPH3)], known as "Vaska's compound'. Excess Co gives a five coordinated species and treatment with NaBH in ethanol gives [IrH(CO)2 (PPH3)2]. Derive a formal name for 'Vaska's compound'. Draw and name all isomers of the two five-coordinate complexes.

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

SAIC Pr7.1 The compound Na,lrCl, reacts with triphenylphosphine in diethyleneglycol in an
atmosphere of CO to give trans-[IrCI(CO)(PPH3)2], known as 'Vaska's compound'. Excess
Co gives a five coordinated species and treatment with NaBH in ethanol gives [IrH(CO)2
(PPH3)2]. Derive a formal name for 'Vaska's compound'. Draw and name all isomers of the
two five-coordinate complexes.

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