The anticancer drug cisplatin, cis-[Pt(NH3)2Cl2] (see Figs. 8.12b and 8.33),can be prepared from K2PtCl6 via reduction with N2H4 (hydrazine), givingK2PtCl4, followed by replacement of two chloride ion ligands with ammonia. Give systematic names to the three platinum complexes referred to inthis statement.

Q: Amines, NR3, are usually only weakly coordinating toward low valent metals. why is this so?Do you…

A: #Part-1: π-acceptor ligands or π-acid ligands like CO act as good ligands due to the presence of…

Q: State the types of isomerism that may be exhibited by the following complexes, and draw structures…

A: Geometrical isomers and optical isomers are two types of isomers that can exist in coordination…

Q: (a) For Co(NH3)63+, give the LFT diagram, with electrons included as well as Aoct, HOMO, LUMO, LFSE…

A: The full form of LFT is Ligand Field Theory (LFT). To construct this LFT diagram for Co(NH3)63+, we…

Q: 1. Give the formula for each of the following and draw their structures. Also indicate the type of…

A: Compounds in which transition metal atoms are bonded with ligands through coordinate or dative bonds…

Q: sketch a simple orbital overlap diagram to show how a bridging ligand can facilitate the coupling of…

A: Antiferromagnetism is a type of magnetism in which adjacent ions or electrons are aligned in…

Q: 19.6 Identify the probable type of isomerism for (a) Co(en)3C13 (b) Cr(NH3)3C13 мин

A:

Q: Coordination compounds of formula MA4 might be square planar or tetrahedral. How many isomers would…

A: This can be explained by Valance Bond Theory of coordination compound.

Q: For the following compound (i) draw the structures to represent the possible isomers, (ii) label as…

A:

Q: Give formulas and the geometry around the central metal ion corresponding to the following; a)…

A:

Q: None

A: (a) Determining Transitions Using the Orgel Diagram:The Orgel diagrams are used to predict the…

Q: Werner prepared two compounds by heating a solution of PtCl₂ with triethyl phosphine, P(C₂H₅)₃,…

A: From given percentage values the moles of each element is calculated as shown below, Pt moles=38.8g…

Q: Account for the fact that the colours, and their intensities, exhibited by transition metal…

A: Transition metal complexes can exhibit a wide range of colors due to the presence of unpaired…

Q: Write the formula of the following compounds: (a) tetraamminedicyanidomanganese(IV)…

A: Here given, IUPAC name of coordination  compound. The formula of given compound written below...

Q: Cis-diamminedichloroplatinum (II) or “cisplatin” is a square planar complex with the formula…

A: The structure of cis-platin and trans-platin is shown as follows: Among Geometrical Isomers,…

Q: 1. *For each of the following coordination compounds, provide the transition metal oxidation state,…

A: Compound  Ox. No.  Co. No.  Shape d e- s Na2[Fe(CO)4] +2 4 tetrahedral 6 [IF6]3- +3 6 Octahedral…

Q: 19.9 Provide systematic names for each of the following compounds: (a) (NH4)2[CuCl4]; (b)…

A: •Here given compounds are:- A. (NH4)2[CuCl4]B. [Co(NH3)5(OH2)]Br3C. K3[Cr(CO)4]D. K2[NiF6]E.…

Q: The coordination complex (complex 1) shown below displays isomerism. Coordination compounds…

A: Since we only answer up to 3 sub-parts, we’ll answer the first 3. Please resubmit the question and…

Q: (iv) In transition metal complexes such as those in part (a)(i), what determines the wavelength of…

A: 1) [Fe(h2o)6]+3 oxidation number +3 and d5 high spin configuration [Fe(CN)6]-3 oxidation number +3…

d-Block Elements

According to the modern form of periodic table, 118 elements are present which are subdivided as four blocks, namely, s, p, d and f-block elements based on the entry of the valence electron or last electron into which orbital.