State the types of isomerism that may be exhibited by the following complexes, and draw structures of the isomers: (a) [Co(en)2 (ox)], (b) [Cr(ox)2(OH₂)2], (c) [PtCl₂ (PPh3)2], (d) [PtCl2 (Ph₂PCH₂CH₂PPh₂)] and (e) [Co(en) (NH3)2Cl₂].

Q: Name each of the compounds or ions given. (a) [Co(en)2(NO2)Cl]+(b) [Co(en)2Cl2]+(c) [Pt(NH3)2Cl4](d)…

A: Given compounds and ions    (a) [Co(en)2(NO2)Cl]+   (b) [Co(en)2Cl2]+   (c) [Pt(NH3)2Cl4]   (d)…

Q: Determine the oxidation state of metals and its electronic configuration for the following complexes…

A: To determine the oxidation state of metals and their electronic configurations in the given…

Q: 5. (a) (b) The complex ion NiC4² has two unpaired electrons, whereas Ni(CN)42 is diamagnetic.…

A: Tetrahedral complex : If in tetra coordinated complex pairing of electrons doesn't occur then…

Q: Nickel (II) complexes in which the metal coordination number is 4 can have either tetrahedral or…

A: The objective of the question is to explain why [NiCl4]2- is paramagnetic and [Ni(CN)4]2- is…

Q: 3. Give the draw the d orbital diagram and give electron count, state whether the metal is high…

A:

Q: Q2 a) Name the following complexes: KĄ[PtBrg], Fe[Fe(CN)6], [Cr(en)3]Cl3 b) Draw the complex…

A:

Q: Predict the structures of platinum-containing products A and B in the following reactions and…

A: Since you have asked multiple questions, we will solve the first question for you. If you want any…

Q: Give the number of d electrons (n of dn) for the central metal ion in (a) [Cr(H2O)6](ClO3)2; (b)…

A: Electronic configuration is used to describe how the electrons of an atom/ion are distributed in the…

Q: 3. Specify whether the following complexes hav (a) tetrahedral [Ni(CO)2(Cl)₂] 10 (b) [Pt(en)₂Cl₂]Cl₂…

A: Isomers are chemical compounds with which same chemical formula but different structural…

Q: Determine the coordination number (c.n.) and the oxidation state (o.s.) of the transition metal in…

A: Since you have posted a question with multiple sub parts, we will solve first three sub parts for…

Q: c) Draw the structure of each of the following complexes. Clearly show the stereocentre of central…

A: Structure of complex compound:A complex compound is a molecular structure with a central atom…

Q: Name the following complex compounds: [Pt(NH3)2Cl3]+ [Co(NH3)2(H2O)2Cl2]+ [Co(NH3)2(H2O)2BrCl]+…

A: Naming coordination complexes involves a set of rules established by the International Union of Pure…

Q: Which of the following compounds can exhibit cis-trans isomerism? O [Fe(CO)2(NH3)2]²* O [Zn(CO)5Br]*…

A: Suitably substituted square planar and octahedral complexes can show the cis-trans isomerism.…

Q: Write the hybridization and shape of the following complexes: (i) [CoF6]3- (ii) [Ni(CN)4]2- (Atomic…

A: The hybridisation and shape of the given compounds are

Q: Write a balanced net ionic equation for the reaction of [Cr(C₂H3O2)2(H₂O)]2 with air in the presence…

A: We have find out the answer.

Q: Name the following compounds and draw their structures: (5) a) [Fe(OH)( H2O)5] Cl2 b) Li[Cr(OH)4] c)…

A: The objective of the question is to name the given compounds and draw their structures. The…

Q: c) Draw the structure of each of the following complexes. Clearly show the geometry at the central…

A: Here we have to draw the structure of each metal complexes and the geometry of central metal ion- A…

Q: Which of the following complexes is "inert" in regards to ligand substitution reactions? Group of…

A: The number of d-electrons, configuration, size of the metal and charge of the metal decides the…

Q: Describe the state of hypridisation , shape and the magnetic behavior of the following complexes :…

A:

Q: Diamagnetic complexes of cobalt (III) like [Co(NH3)6]3+ and [Co(en)3]3+ are orange- yellow, while…

A: Molecular orbital diagram helps us in understanding the electronic energy levels of molecules. If we…

Q: Identify each of the following pairs of coordination compounds as coordination isomers, linkage…

A: Since you are asked for multiple sub-parts, we are entitled to solve first three only.

Q: 1) Is it possible to have isomers of the following coordination compounds? If this is the case,…

A: Tetrahedral complexes with 4 different ligands show optical isomerism Octahedral complexes of Ma4b2…

Q: Sketch the following complexes. If more than one enantiomer exists, sketch just one. (a)…

A: Given -> -> In mer isomer three groups are on same plane , whereas in fac three similar groups…

Q: 5. (a) (b) The complex ion NiC14² has two unpaired electrons, whereas Ni(CN)4² is diamagnetic.…

A: This question is based on bonding in coordination compounds.

Q: You have a solution of the following ion: [Fe(H2O)6]3+ a) Is the ion more likely paramagnetic or…

A: In the crystal field theory, the paring of electrons in the splitted state does not take place for…

Q: What is the charge on each of the following complex ions? hexaaquairon(II), [Fe(H2O)6]?…

A: 1.) Charge on hexaaquairon(II) Is +2   The oxidation state or charge on the central metal ion, Fe =…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.