Q5. (i) pentacarbonyl complex with (1) a primary amine, NH2R', and (2) a secondary amine, NHR'2. Draw the molecule structure of both end products. N.B. Consider the amines as NR2 + 2H* (protonated imide group) and NR',¯ +H* Briefly describe the reaction of the above dithiocarbene ligand in the depicted tungsten (protonated amide group). (ii) (reaction (1)), but starting instead with the complex [W(CO)s(CN)] ¯and using a different Suggest an alternative route to the product obtained with the primary amine NHR' appropriate reagent Y. co CO + NH2R' ?? CO OC. Y CO SR oc OC ENI CO CO SR co ICO + NHR'2 ?? SR CO SR 8.
Q5. (i) pentacarbonyl complex with (1) a primary amine, NH2R', and (2) a secondary amine, NHR'2. Draw the molecule structure of both end products. N.B. Consider the amines as NR2 + 2H* (protonated imide group) and NR',¯ +H* Briefly describe the reaction of the above dithiocarbene ligand in the depicted tungsten (protonated amide group). (ii) (reaction (1)), but starting instead with the complex [W(CO)s(CN)] ¯and using a different Suggest an alternative route to the product obtained with the primary amine NHR' appropriate reagent Y. co CO + NH2R' ?? CO OC. Y CO SR oc OC ENI CO CO SR co ICO + NHR'2 ?? SR CO SR 8.
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Q5.
(i)
pentacarbonyl complex with (1) a primary amine, NH;R', and (2) a secondary amine, NHR'2.
Draw the molecule structure of both end products.
N.B. Consider the amines as NR2 + 2H* (protonated imide group) and NR',¯ +H*
Briefly describe the reaction of the above dithiocarbene ligand in the depicted tungsten
(protonated amide group).
(ii)
(reaction (1)), but starting instead with the complex [W(CO)s(CN)]¯and using a different
Suggest an alternative route to the product obtained with the primary amine NHR'
appropriate reagent Y.
co
CO
+ NH2R'
??
CO
OC.
Y
CO
SR
oc
OC
ENI
CO
CO
SR
co
ICO
+ NHR'2
??
SR
o'
SR
8.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc0a47489-4bc6-41ee-b766-5307950d0ffd%2Ff627be34-aaad-436f-b892-994d0f74b9ce%2Fq6k455f_processed.png&w=3840&q=75)
Transcribed Image Text:Q5.
(i)
pentacarbonyl complex with (1) a primary amine, NH;R', and (2) a secondary amine, NHR'2.
Draw the molecule structure of both end products.
N.B. Consider the amines as NR2 + 2H* (protonated imide group) and NR',¯ +H*
Briefly describe the reaction of the above dithiocarbene ligand in the depicted tungsten
(protonated amide group).
(ii)
(reaction (1)), but starting instead with the complex [W(CO)s(CN)]¯and using a different
Suggest an alternative route to the product obtained with the primary amine NHR'
appropriate reagent Y.
co
CO
+ NH2R'
??
CO
OC.
Y
CO
SR
oc
OC
ENI
CO
CO
SR
co
ICO
+ NHR'2
??
SR
o'
SR
8.
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