Researchers first discovered in 1973 that chlorofluorocarbons (CFCS) were depleting the Earth's ozone layer when released into the atmosphere. Once they reach the stratosphere, CI is released from the CFCS molecules by interaction with UV light. Free Cl atoms are able to react with ozone in a catalytic cycle that converts Os into the more stable O2. It is estimated that a single Cl atom is able to react with_ 100000 Os molecules. Although CFCS production was banned in 1996, there are still a substantial number of motor vehicle air conditioners (MVACS) that use CFC-12 (CF:Ch) as refrigerant. The average CFC-12 emission rate from operating MVACS has been estimated to be 59.5 mg per hour per vehicle (Zhang et al. Environ. Sci. Technol. Lett. 2017). How much chlorine, in kg, is added to the atmosphere in a year due to 100 million MVACS using CFC-12 as refrigerant?

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Researchers first discovered in 1973 that chlorofluorocarbons (CFCS) were depleting the Earth's
ozone layer when released into the atmosphere. Once they reach the stratosphere, CI
is released from the CFCS molecules by interaction with UV light. Free Cl atoms are
able to react with ozone in a catalytic cycle that converts Os3 into the more stable O2.
It is estimated that a single Cl atom is able to react with_ 100000 O3 molecules.
Although CFCS production was banned in 1996, there are still a substantial number
of motor vehicle air conditioners (MVACS) that use CFC-12 (CF2CI2) as refrigerant.
The average CFC-12 emission rate from operating MVACS has been estimated to
be 59.5 mg per hour per vehicle (Zhang et al. Environ. Sci. Technol. Lett. 2017).
How much chlorine, in kg, is added to the atmosphere in a year due to 100 million
MVACS using CFC-12 as refrigerant?
Transcribed Image Text:Researchers first discovered in 1973 that chlorofluorocarbons (CFCS) were depleting the Earth's ozone layer when released into the atmosphere. Once they reach the stratosphere, CI is released from the CFCS molecules by interaction with UV light. Free Cl atoms are able to react with ozone in a catalytic cycle that converts Os3 into the more stable O2. It is estimated that a single Cl atom is able to react with_ 100000 O3 molecules. Although CFCS production was banned in 1996, there are still a substantial number of motor vehicle air conditioners (MVACS) that use CFC-12 (CF2CI2) as refrigerant. The average CFC-12 emission rate from operating MVACS has been estimated to be 59.5 mg per hour per vehicle (Zhang et al. Environ. Sci. Technol. Lett. 2017). How much chlorine, in kg, is added to the atmosphere in a year due to 100 million MVACS using CFC-12 as refrigerant?
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