For the reversible, one-step reaction, k₁ A+A= B+C K= k_1 the rate constant for the forward reaction, k₁, is 265 L-mol-¹.min-¹ and the rate constant for the reverse reaction, k₁, is 385 L.mol-¹-min-¹ at a given temperature. The activation energy for the forward reaction is 42.9 kJ.mol-¹, whereas the activation energy for the reverse reaction is 23.0 kJ.mol-¹. Determine the equilibrium constant, K, of this reaction.

Chemistry: The Molecular Science
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Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 53QRT: For the reaction of iodine atoms with hydrogen molecules in the gas phase, these rate constants were...
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For the reversible, one-step reaction,
A + A
k₁
K =
k-1
B + C
the rate constant for the forward reaction, k₁, is 265 L·mol¯¹·min¯¹ and the rate constant for the reverse reaction, k₁, is
385 L·mol¯¹·min¯¹ at a given temperature. The activation energy for the forward reaction is 42.9 kJ.mol-¹, whereas the
activation energy for the reverse reaction is 23.0 kJ.mol-¹.
Determine the equilibrium constant, K, of this reaction.
Transcribed Image Text:For the reversible, one-step reaction, A + A k₁ K = k-1 B + C the rate constant for the forward reaction, k₁, is 265 L·mol¯¹·min¯¹ and the rate constant for the reverse reaction, k₁, is 385 L·mol¯¹·min¯¹ at a given temperature. The activation energy for the forward reaction is 42.9 kJ.mol-¹, whereas the activation energy for the reverse reaction is 23.0 kJ.mol-¹. Determine the equilibrium constant, K, of this reaction.
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