Radon (Rn) is the heaviest, and only radioactive, member ofGroup 8A(18) (noble gases). It is a product of the disintegrationof heavier radioactive nuclei found in minute concentrations inmany common rocks used for building and construction. In recent years, health concerns about the cancers caused from in-haled residential radon have grown. If 1.0x10^15atoms of ra-dium (Ra) produce an average of 1.373x10^4atoms of Rn persecond, how many liters of Rn, measured at STP, are producedper day by 1.0 g of Ra?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Radon (Rn) is the heaviest, and only radioactive, member ofGroup 8A(18) (noble gases). It is a product of the disintegrationof heavier radioactive nuclei found in minute concentrations inmany common rocks used for building and construction. In recent years, health concerns about the cancers caused from in-haled residential radon have grown. If 1.0x10^15atoms of ra-dium (Ra) produce an average of 1.373x10^4atoms of Rn persecond, how many liters of Rn, measured at STP, are producedper day by 1.0 g of Ra?

Expert Solution
Step 1

The volume of radon at the STP produced by the 1 g of Radium is to be determined.

Step 2

Mass of the radium given = 1 g

Molar mass of radium = 226 g/mol

Thus, the number of moles of radium is the ratio of the mass of the radium given to the molar mass of radium.

Thus,

                                nR = 1 g226 g/mol = 0.004425 mol

nR = Number of moles of radium

Step 3

Let Avogadro number = NA = 6.22 x 1023 atoms

The number of atoms of radium present is given as:-

                                     NR = nR × NANR = 0.004425 × 6.22 × 1023 atomsNR = 2.75 × 1021 atoms

NR = Number of atoms of radium

Step 4

Let the number of atoms of radon produced by radium = Z

It is given that 1 x 1015 atoms of radium produces 1.373 x 104 atoms of radon per second.

Thus,

                                Z = 1.373 × 1041015 × 2.75 × 1021 atoms/secZ = 3.77575 × 1010 atoms/sec1 day = 86400 secZ = 3.77575 × 1010 × 86400 atoms/dayZ =3.26 × 1015 atoms/day

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