Question 3. Consider the reaction scheme below. Under the proper reaction conditions this transformation works anc delivers a 36% yield of the product shown. 好一 H H HN HN NH NH - N1N H H a. Determine what reaction conditions are necessary: heat or light b. Illustrate the key HOMO/LUMO interaction(s) necessary to rationalize your answer to part a. You do not need to draw the entire molecule for this task, just the alkenes since those are the groups undergoing the reaction.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Question 3. Consider the reaction scheme below. Under the proper reaction conditions this transformation works anc
delivers a 36% yield of the product shown.
HN
NH
HN
HH
a. Determine what reaction conditions are necessary: heat or light
b. Illustrate the key HOMO/LUMO interaction(s) necessary to rationalize your answer to part a. You do not need to draw
the entire molecule for this task, just the alkenes since those are the groups undergoing the reaction.
Transcribed Image Text:Question 3. Consider the reaction scheme below. Under the proper reaction conditions this transformation works anc delivers a 36% yield of the product shown. HN NH HN HH a. Determine what reaction conditions are necessary: heat or light b. Illustrate the key HOMO/LUMO interaction(s) necessary to rationalize your answer to part a. You do not need to draw the entire molecule for this task, just the alkenes since those are the groups undergoing the reaction.
c. Why does the product below not form? What does the fact that all the hydrogens are syn to one another tell you about
the arrangement of the two six-membered rings in the transition state?
HN
Transcribed Image Text:c. Why does the product below not form? What does the fact that all the hydrogens are syn to one another tell you about the arrangement of the two six-membered rings in the transition state? HN
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