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8. Classify each reaction as Sy1, Sy2, El or E2. NaNa THE (a) CH3CH2CH2CH2Br CH3CH2CH2CH2N=N=N (b) CI CH3CH2CHCH2CH3 кон Ethanol CH3CH,CH=CHCH3 (c) OČCH3 CH3 CI -CH3 CH,CO,H,

8. Classify each reaction as Sy1, Sy2, El or E2. NaNa THE (a) CH3CH2CH2CH2Br CH3CH2CH2CH2N=N=N (b) CI CH3CH2CHCH2CH3 кон Ethanol CH3CH,CH=CHCH3 (c) OČCH3 CH3 CI -CH3 CH,CO,H,

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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8. Classify each reaction as Sy1, Sy2, El or E2. (a) CH3CH2CH2CH2Br NaNa THE CH3CH2CH2CH2N=N=N (b) CI CH3CH2CHCH2CH3 кон Ethanol CH3CH2CH=CHCH3 (c) CI OČCH3 -CH3 CH,CO-H, CH3
Transcribed Image Text:8. Classify each reaction as Sy1, Sy2, El or E2. (a) CH3CH2CH2CH2Br NaNa THE CH3CH2CH2CH2N=N=N (b) CI CH3CH2CHCH2CH3 кон Ethanol CH3CH2CH=CHCH3 (c) CI OČCH3 -CH3 CH,CO-H, CH3
4. Predict whether each of the following substitution reactions is likely to be Sylor CH,C0, Na CH,COM H0 Sy2. a. CH2Br CH2OAC CH,CO, Na DMF b. HO. HCI CH3OH CH3 CH3 Na* SCH3 CH3CN 5. Setting aside the double bond stereochemistry, what products would you expect from elimination reactions of the following alkyl halides? H2C=CH2Br d. H2C=CH,SCH3 CH3 çI CH3 CH3CHCH2-C-CHCH3 CH3 6. From what alkyl halides are the following alkenes have been made? CH3 CH3 CH3CHCH2CH2ČHCH=CH2 7. Which of the two isomers would you expect to undergo E2 elimination faster? trans-1-bromo 4-rert-butylcyclohexane or cis-1-bromo-4-rert-butylcyclohexane? Draw each molecule in its more stable chair conformation. Provide an explanation to your answer.
Transcribed Image Text:4. Predict whether each of the following substitution reactions is likely to be Sylor CH,C0, Na CH,COM H0 Sy2. a. CH2Br CH2OAC CH,CO, Na DMF b. HO. HCI CH3OH CH3 CH3 Na* SCH3 CH3CN 5. Setting aside the double bond stereochemistry, what products would you expect from elimination reactions of the following alkyl halides? H2C=CH2Br d. H2C=CH,SCH3 CH3 çI CH3 CH3CHCH2-C-CHCH3 CH3 6. From what alkyl halides are the following alkenes have been made? CH3 CH3 CH3CHCH2CH2ČHCH=CH2 7. Which of the two isomers would you expect to undergo E2 elimination faster? trans-1-bromo 4-rert-butylcyclohexane or cis-1-bromo-4-rert-butylcyclohexane? Draw each molecule in its more stable chair conformation. Provide an explanation to your answer.
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