Question 1 1 pts Identify the major product when the following compound (2-methyl-2-pentene) is heated with NBS (Hint: Consider resonance of the free radical formed) (CH3)2C=CHCH2CH3 ● (CH3)2C(Br)CH=CHCH3 O (CH3)2C-CHCH(Br)CH3 ● (CH3)2C(Br)-CHCH2CH3 (CH3)2C (Br)CH (Br) CH2CH3 DQuestion 2 Desk 1 M acer 1 pts
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- Questão 10A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis resulted in CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. What is the reasonable structure for this hydrocarbon? Hexadec-6,10-dino undec-1,5-dino Hept-1,5-dino hex-1,5-dino nahFollowing is a balanced equation for the allylic bromination of propene. CH2==CHCH3 + Br2 h CH2==CHCH2Br + HBr (a) Calculate the heat of reaction, H 0, for this conversion. (b) Propose a pair of chain propagation steps and show that they add up to the observed stoichiometry. (c) Calculate the H 0 for each chain propagation step and show that they add up to the observed H 0 for the overall reaction.The reaction of 3-methylene-1-cyclohexene and HBr yields the four products shown in the attachment. Which two are formed at high temperatures and which two are formed at low temperatures? Why? Why is 1-bromo-3-methylenecyclohexane not formed?
- Name the following molecule, including any stereochemistry, using IUPAC naming rules. (Hint: Newman projections are from Chapter 2, section 5). As a reminder, the prefix for a bromine atom is "bromo." Br H H H CH₂CH3 CH3 Answer: (2S)-2-bromopentane XWhich of the following is the product of the reaction of (R)-1-deutero-1-chloropropane with methoxide? (R)-CH3-CH2-O-CH3 (R)-CH3-CH2-CHCl-O-CH3 (S)-CH3-O-CHD-CH2-CH3 (S)-CH3-CH(O-CH3)-CH2D none of theseElimination reactions of cis- and trans-1-bromo-2-methylcyclohexanes with Eto in ETOH could potentially give the two products, 1-methylcyclohexene (1) or 3-methylcyclohexene (2). Which answer (a-d) indicates the major products for each reaction? Br „Br EtO Eto "CH3 ELOH `CH3 *CH ELOH "CH3 cis trans Select one: a. 2 from the cis and 1 from the trans substrate b. 2 both from the cis and trans substrates c. 1 both from the cis and trans substrates d. 1 from the cis and 2 from the trans substrate
- 11) Which of the following reagents should be used to convert 3-octyne to (E)-3-octene? A) Na, NH3 B) H2, Lindlar's catalyst C) H2SO4, H20 D) HgSO4, H20 E) H2, Pt Page | 5 12) What is the major product in the following reaction CH3 1) BH3/THF 2) H2O2/NAOH HOL CH3 CH3 CH3 HOll OH VOH HO A C B 13) In the following reaction, identify the major product. 0.00 (00.00 0 OH KHSO, rlos OH A 419/3.12-6 OH etads EDetermine the product(s) formed when cyclohexane is tested with the following reagents.An alkene having the molecular formula C6H₁2 is treated sequentially with ozone (03) and zinc/acetic acid to give the product/s shown. O Draw a structural formula for the alkene. H3C 1 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. + ▾ CH3 will n [F ChemDoodleⓇ 16
- curri ENO 18) C3 Complete and balance the following reactions a) CH-CH-CH-CH₂ + Bri REAGENTS b) D-Test with potassium permanganate (KMnO4) D.1 Observe the color change. Write (Yes = reaction and NR= no reaction) in the following reactions Condensed structural formulas CI PRODUCTS IF REACTION OCCURS 00:00 Hydrocarbon Cyclohexane (CHz) Cyclohexene (CaH10) Toluene D.2 Draw the condensed structural formula of the reactants and products if any reaction occurred. (CrHe) Reaction with KMnO CICLOHEXANE (C6H12) CICLOHEXENO (C6H10) TOLUENE (CaHoWhich functional group(s) would be added to 1-methylcyclohexene using the reagents below: H3O+ hydrogen hydroxyl ketone and aldehyde bromine and hydroxyl bromine and hydrogen bromine hydrogen and hydroxyl aldehyde ketone Save for LaterWhen the alkene A was treated first with Hg(OAc)2 in MeOH and second with NaBH4 the product was the ether B. Using curved arrows please give the mechanism for the first step of (Hg(OAc)2 in MeOH) this reaction, including any regioselectivity or stereoselectivity. H3C 1. Hg(OAc)2, MeOH H3C O-CH3 =CH2 ✓ -CH3 H3C 2. NaBH H3C A B