Question 1 1 pts Identify the major product when the following compound (2-methyl-2-pentene) is heated with NBS (Hint: Consider resonance of the free radical formed) (CH3)2C=CHCH2CH3 ● (CH3)2C(Br)CH=CHCH3 O (CH3)2C-CHCH(Br)CH3 ● (CH3)2C(Br)-CHCH2CH3 (CH3)2C (Br)CH (Br) CH2CH3 DQuestion 2 Desk 1 M acer 1 pts
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- Following is a balanced equation for the allylic bromination of propene. CH2==CHCH3 + Br2 h CH2==CHCH2Br + HBr (a) Calculate the heat of reaction, H 0, for this conversion. (b) Propose a pair of chain propagation steps and show that they add up to the observed stoichiometry. (c) Calculate the H 0 for each chain propagation step and show that they add up to the observed H 0 for the overall reaction.Which of the following is the product of the reaction of (R)-1-deutero-1-chloropropane with methoxide? (R)-CH3-CH2-O-CH3 (R)-CH3-CH2-CHCl-O-CH3 (S)-CH3-O-CHD-CH2-CH3 (S)-CH3-CH(O-CH3)-CH2D none of theseElimination reactions of cis- and trans-1-bromo-2-methylcyclohexanes with Eto in ETOH could potentially give the two products, 1-methylcyclohexene (1) or 3-methylcyclohexene (2). Which answer (a-d) indicates the major products for each reaction? Br „Br EtO Eto "CH3 ELOH `CH3 *CH ELOH "CH3 cis trans Select one: a. 2 from the cis and 1 from the trans substrate b. 2 both from the cis and trans substrates c. 1 both from the cis and trans substrates d. 1 from the cis and 2 from the trans substrate
- Determine the product(s) formed when cyclohexane is tested with the following reagents.Which of the following compounds would not be a product of the reaction of 2-bromo-3-methylpentane in ethanol? (Ethoxy = -OCH2CH3) 3-methylpent-1-ene 2-ethoxy-3-methylpentane 1-ethoxy-3-methylpentane 3-methylpent-2-ene 2-ethylbut-1-eneDraw a structural formula for the major organic product of the reaction shown below. CH₂ C(CH3)3 (1) H3C 2 + CuLi You do not have to consider stereochemistry. Ⓡ Sn [F ? ChemDoodle Ⓡ ether H₂O +
- Please hurry1c) What will be the product of the following reaction? O₂N >> + -Br (HO)₂B- Pd(OAc)₂ Degassed H₂O/AcetoneDraw a structural formula for the major organic product of the following reaction: CH3 CH3 ● CH3 CH3 AAVIL + Br₂ Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. ● If enantiomers are formed, just draw one. CH₂Cl₂ Sn [F ? ChemDoodleⓇ
- Which of the following reagents would you use to prepare Chlorocyclopentane from cyclopentene? OC2 / H20 NBS / H20, DMSO OCh/ CH,Cl2 HCIFill in the missing products below. 1) Hg(OAc)2, EtOH 2) NaBH4 Excess HI A B Heat RCO3H 1) H-CEC: Na D 1) NaSEt 2) H3O+ 2) H₂O+ → E HBr → FDraw a structural formula for the alkene with the molecular formula C5H10 that reacts with Br2 to give each product.