16) Which of the following will give 2-methyl-1-butene as the only alkene product on treatment with KOC(CH3)3 in dimethyl sulfoxide? A) 2-bromo-3-methylbutane C) 2-bromo-2-methylbutane B) 1-bromo-3-methylbutane D) 1-bromo-2-methylbutane

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Do any 1 of the following questions
15) The compound below is a
isomer
HO
H2C
CH2
HS
A) E isomer B) Z isomer C) R isomer D) S isomer
16) Which of the following will give 2-methyl-1-butene as the only alkene product on
treatment with KOC(CH3)3 in dimethyl sulfoxide?
A)
2-bromo-3-methylbutane
B)
1-bromo-3-methylbutane
C)
2-bromo-2-methylbutane
D)
1-bromo-2-methylbutane
17) If S glutamic acid has a specific rotation of +31.5°, what is the specific rotation of R-
glutamic acid?
A) -15.8° B)-31.5° C) -63.0° D) +63.0° E) +31.5°
18) In the following reaction,
NaSH, solvent
F.
Br
A) The F is replaced by a -SH, the reaction goes via SN2 and is faster in a polar aprotic so
B) The Br is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic sc
C) The F is replaced by a-SH, the reaction goes via SN' and is faster in a polar protic so
D) The Br is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprotic
E) None of these is true
Transcribed Image Text:15) The compound below is a isomer HO H2C CH2 HS A) E isomer B) Z isomer C) R isomer D) S isomer 16) Which of the following will give 2-methyl-1-butene as the only alkene product on treatment with KOC(CH3)3 in dimethyl sulfoxide? A) 2-bromo-3-methylbutane B) 1-bromo-3-methylbutane C) 2-bromo-2-methylbutane D) 1-bromo-2-methylbutane 17) If S glutamic acid has a specific rotation of +31.5°, what is the specific rotation of R- glutamic acid? A) -15.8° B)-31.5° C) -63.0° D) +63.0° E) +31.5° 18) In the following reaction, NaSH, solvent F. Br A) The F is replaced by a -SH, the reaction goes via SN2 and is faster in a polar aprotic so B) The Br is replaced by a -SH, the reaction goes via SN' and is faster in a polar protic sc C) The F is replaced by a-SH, the reaction goes via SN' and is faster in a polar protic so D) The Br is replaced by a -SH, the reaction goes via SN? and is faster in a polar aprotic E) None of these is true
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