Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Draw the mechanism from the reactants to the product shown in the picture.
What role do the nitro groups play electronically? Why would the reaction be much slower if these nitro groups weren’t attached to those benzene carbons? Draw structures to support answer
![This diagram represents a chemical reaction involving aromatic compounds and the formation of a new compound through a multi-step reaction.
### Reactants
1. **Starting Compound:**
- The first compound on the left is a benzene ring with two nitro groups (NO₂) attached. One nitro group is attached at the top (meta position), and another is attached at the bottom (ortho position). An aldehyde group (CHO) is also attached to the benzene ring at the para position relative to the bottom nitro group.
### Reaction Conditions
2. **Reaction Conditions:**
- The diagram indicates that the reaction takes place in the presence of a base (HO⁻) in water (H₂O). The notation "2" likely signifies the second step in the reaction sequence.
### Product
3. **Final Product:**
- The final product displayed on the right shows a fused bicyclic ring system with a benzene ring and another six-membered ring. The final structure includes:
- One nitro group (NO₂) attached to the benzene ring.
- A carbonyl group (CHO) attached to the fused ring structure.
- Another nitro group (NO₂) is present on the newly formed ring, indicating a ring closure or addition reaction that resulted in forming a polycyclic compound.
### Reaction Scheme Overview
- The reactants undergo a transformation under basic conditions, leading to the formation of a more complex aromatic compound with a fused ring structure.
This reaction sequence highlights the formation of a complex aromatic structure, showcasing important concepts in organic chemistry such as functional group transformations, aromatic substitution, and ring-closure reactions.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F3ce3bcf0-f6f0-4618-a751-02105c16429a%2F534f4699-9c4f-49cb-ad54-d9261fc7a323%2Fztb08y.jpeg&w=3840&q=75)
Transcribed Image Text:This diagram represents a chemical reaction involving aromatic compounds and the formation of a new compound through a multi-step reaction.
### Reactants
1. **Starting Compound:**
- The first compound on the left is a benzene ring with two nitro groups (NO₂) attached. One nitro group is attached at the top (meta position), and another is attached at the bottom (ortho position). An aldehyde group (CHO) is also attached to the benzene ring at the para position relative to the bottom nitro group.
### Reaction Conditions
2. **Reaction Conditions:**
- The diagram indicates that the reaction takes place in the presence of a base (HO⁻) in water (H₂O). The notation "2" likely signifies the second step in the reaction sequence.
### Product
3. **Final Product:**
- The final product displayed on the right shows a fused bicyclic ring system with a benzene ring and another six-membered ring. The final structure includes:
- One nitro group (NO₂) attached to the benzene ring.
- A carbonyl group (CHO) attached to the fused ring structure.
- Another nitro group (NO₂) is present on the newly formed ring, indicating a ring closure or addition reaction that resulted in forming a polycyclic compound.
### Reaction Scheme Overview
- The reactants undergo a transformation under basic conditions, leading to the formation of a more complex aromatic compound with a fused ring structure.
This reaction sequence highlights the formation of a complex aromatic structure, showcasing important concepts in organic chemistry such as functional group transformations, aromatic substitution, and ring-closure reactions.
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