Q.29. Determine, at 298 K, A H°, the standard enthalpy of the reaction (1) between hydroquinone with hydrogen peroxide to produce quinone. CH4(OH)2(aq) + H2O2(aq) → CH,O2(aq) + 2 H,O (() (1) Knowing the standard reaction enthalpies, at 298 K, of the following reactions: (2) H2 (g) + O2 (g) –→ H2O2 (aq) К4) CH4(OH)2 (aq) → CH4O2 (aq) + H2 (g) A2H° = + 177.4 kJ mol-1 (3) A3H° = -191.2 kJ mol-1 %3D Н. (g) + Y.0- (g) — Н-0 (g) A4H° = -241.8 kJ mol-1 (5) H,O (g) → H20 (E) AŞH° = -43-8 kJ mol-1

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Q.29. Determine, at 298 K, A„H°, the standard enthalpy of the reaction (1) between
hydroquinone with hydrogen peroxide to produce quinone.
СоН.(ОН),(аq) + H-0-(aq) — СH,0-(aq) + 2 H0 ()
(1)
Knowing the standard reaction enthalpies, at 298 K, of the following reactions:
(2)
СоНА(ОН)2 (аq) — СеН,О2 (аq) + H-(g)
A2H° = + 177.4 kJ mol-1
(3)
H2 (g) + O2 (g) –→ H2O2 (aq)
A3H° = -191.2 kJ mol-1
(4)
H2 (g) + ½O2 (g) → H2O (g)
A«H° = -241.8 kJ mol-1
(5)
H2O (g) → H2O (€)
AşH° = -43.8 kJ mol-1
Transcribed Image Text:Q.29. Determine, at 298 K, A„H°, the standard enthalpy of the reaction (1) between hydroquinone with hydrogen peroxide to produce quinone. СоН.(ОН),(аq) + H-0-(aq) — СH,0-(aq) + 2 H0 () (1) Knowing the standard reaction enthalpies, at 298 K, of the following reactions: (2) СоНА(ОН)2 (аq) — СеН,О2 (аq) + H-(g) A2H° = + 177.4 kJ mol-1 (3) H2 (g) + O2 (g) –→ H2O2 (aq) A3H° = -191.2 kJ mol-1 (4) H2 (g) + ½O2 (g) → H2O (g) A«H° = -241.8 kJ mol-1 (5) H2O (g) → H2O (€) AşH° = -43.8 kJ mol-1
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