Q.1 The gas-phase decomposition of azomethane, AZO, to give ethane and nitrogen - (CH3)2N2 C2H6 + N2 Experimental observations show that the rate of formation of ethane is first order with respect to AZO at pressures greater than 1 atm (relatively high concentrations) and second order at pressures below 50 mmHg (low concentrations). We could combine these two observations to postulate a rate law of the form -razo = K1CAZO 1+k₂CAZO Find a mechanism that is consistent with the experimental observations. A+ 500 V the himalculation times the roto at 100 K Find the

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 39QAP: The decomposition of azomethane, (CH3)2N2, to nitrogen and ethane gases is a first-order reaction,...
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Q.1
The gas-phase decomposition of azomethane, AZO, to give ethane and nitrogen
-
(CH3)2N2 C2H6 + N2
Experimental observations show that the rate of formation of ethane is first order with
respect to AZO at pressures greater than 1 atm (relatively high concentrations) and
second order at pressures below 50 mmHg (low concentrations). We could combine these
two observations to postulate a rate law of the form -razo =
K1CAZO
1+k₂CAZO
Find a mechanism that is consistent with the experimental observations.
A+
500 V the
himalculation
times the roto at
100 K
Find the
Transcribed Image Text:Q.1 The gas-phase decomposition of azomethane, AZO, to give ethane and nitrogen - (CH3)2N2 C2H6 + N2 Experimental observations show that the rate of formation of ethane is first order with respect to AZO at pressures greater than 1 atm (relatively high concentrations) and second order at pressures below 50 mmHg (low concentrations). We could combine these two observations to postulate a rate law of the form -razo = K1CAZO 1+k₂CAZO Find a mechanism that is consistent with the experimental observations. A+ 500 V the himalculation times the roto at 100 K Find the
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