(Q-4) Consider the dissociation equilibrium of chlorine gas; Cl₂(g) = 2Cl(g) Energy (T298.15 K) AG°, kJ/mol AH°, kJ/mol CI 105.7 121.3 Cl₂ 0.0 0.0 a) Derive an expression for Kp as a function of the degree of dissociation, a and total pressure P. b) Calculate Kp at 298.15 K. c) Calculate Kp at 1000 K.

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(Q-4) Consider the dissociation equilibrium of chlorine gas;
Cl₂(g) = 2Cl(g)
Energy (T298.15 K)
AG°, kJ/mol
ΔΗ°, kJ/mol
CI
105.7
121.3
Cl₂
0.0
0.0
a) Derive an expression for Kp as a function of the degree of dissociation, a and total pressure P.
b) Calculate Kp at 298.15 K.
c) Calculate Kp at 1000 K.
Transcribed Image Text:(Q-4) Consider the dissociation equilibrium of chlorine gas; Cl₂(g) = 2Cl(g) Energy (T298.15 K) AG°, kJ/mol ΔΗ°, kJ/mol CI 105.7 121.3 Cl₂ 0.0 0.0 a) Derive an expression for Kp as a function of the degree of dissociation, a and total pressure P. b) Calculate Kp at 298.15 K. c) Calculate Kp at 1000 K.
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