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- Dtermine the reagents that can accomplish the rxn CH2OH (1) Reagent ? (2) Reagent ? C9H1202 (4) Reagent ? (3) H+ a. (1) SOC12 (2) 1-propanol; (4) PCC/pyridine b. (1) NaH, (2) acetone, (4) NABH4 c. (1) NaH, (2) epoxide (4) PCC/pyridine d. (1) Jones reagent, (2) NaH, (4) epoxidePredit ds produc 1. Br ght 2.1-BuOK 38 Which represet soy depis 2mthyleyclohexeol where the wo ubatitum are S.BH, in THE 4 HO, NaOH (A) (m) CH (A) 1014 (B) BH CH OH (C) (D) (9 O он (D) 25. What radical interediate is fonmed in CHa this reaction? CH HC 2 HOOH H,C 30 Which molecules sre chiral? H. hv HO (m) COH Br (C) HO (D) HO V 26. Predict the product OH SOci II IV (A) 1,II, II, & IV (C) H& II pyridine (B) II, II, A IV (D) I1& IV (A) (B) CI 31. Explain why this synthetic route will not produce this product. şoCi 1) CHMgr 2) HHP (C) (D) SOCI H,HO heal Which reagents produce this transformation? 27. (A) The Grigrard reagent will not add to the ketone. OH HO. (B) The Grignard reagent will not add to the alcohol. (A) 1) LIAIH 2) H, H;0 (C) The Markovnikov rule will lead to a different product. (B) NABH,, HO (D) Acid catalyzed dehydration will lead to the formation of the more (C) PCC, CH,Cl; (D) KMNO, NaOH, H;O, heat thermodynamically stable alkene. What is the formal charge of oxygen in…( hlp me
- ( do 1 n 2(20 pts) Alcohol A undergoes a remarkable acid-catalyzed conversion to B. Me Me Me HO Me I Me S Me Me + HA H H (cat.) Me Me Me Me A Hmm Hmm Me Me 11111 Me B Me Me a. Provide a mechanism. It may take a while to draw out all the intermediates, but consider this as a step- by-step process, although one could also imagine mechanistic alternatives where all or some of the steps are concerted. (attach additional page with your mechanism) b. What do you notice about the stereochemistry of each 1,2-shift in your mechanism (or at least where the stereochemistry of the shift is apparent from the structure of B)? c. How many 1,2-shifts are there in total? d. Give a one-word name to the final step in your mechanism.- с app.101edu.co Identify which of the following compounds is meso. I H₂CO H III H C H₂CO HCI Н A) 1 B) II Question 52 of 67 C) III D) IV OCH H₂CO "CH3 H C H CH₂ OCH₂ IV Н H₂CO H.C Н OCH, "H CH3 CH3 OCH₂ S В Sub
