Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter19: Complex Ions
Section: Chapter Questions
Problem 42QAP
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Question
State, with justification, whether you expect nitric oxide (NO) to be a stronger or weaker pi-acceptor ligand than CO?
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Can you summary between your 2 previous answers which one is correct?
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"The π* orbital of NO is partially filled with an unpaired electron, which makes it less efficient in accepting electron density from the metal’s d orbitals. On the other hand, the fully empty pi*orbital of CO can strongly overlap with the metal’s d orbitals, resulting in a stronger π-back bonding interaction and a stronger metal-ligand bond. " Is this correct and makes NO weaker?
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