Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Please, please explain the part I have circled in the pic--I don't understand why the mols of H2SO4 have to be multiplied by 2!
![Ammonium sulphate, an important fertilizer, can be prepared by the reaction of ammonia with sulphuric
acid according to:
2NH, + H,SO, → (NH,),SO,
-
Calculate the volume of NH3 needed at 42°C and 15:6 atm to react with 870 g of H2SO4.
Solution ·
First, the temperature must be changed to K.
T(K) = T(° C) + 273.15
= 42°C + 273.15
%3D
%3D
= 315.15 K
Now, you must convert the given mass into moles.
mol (H2SO4) = mass x MM[H2SO4]
= 870 g/ 98.0784 g/mol
= 887 mol
%3D
%3D
Find the number of moles of NH3 that will reaction with the H,SO4.
From the balanced equation, each mole of H,SO, requires 2 mol of NH
So, 8.87 mol x 2 = 17.74 mol of NH3 is needed.
Fnally use the ideal gas law to calculate the volume of ammonia that will react.
PV = nRT
nRT
V =
(17.74 mol)(0.08206
L•atm
(315.15 K)
K«mol
15.6 atm
= 29.41L
%3D
Therefore, 29.41 L of are needed.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F772c7f7c-b9c8-4bf9-9232-333e27b7b59b%2F5c3f1473-698f-4eb5-9e56-1e48dff11b6a%2Fivd6i7r_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Ammonium sulphate, an important fertilizer, can be prepared by the reaction of ammonia with sulphuric
acid according to:
2NH, + H,SO, → (NH,),SO,
-
Calculate the volume of NH3 needed at 42°C and 15:6 atm to react with 870 g of H2SO4.
Solution ·
First, the temperature must be changed to K.
T(K) = T(° C) + 273.15
= 42°C + 273.15
%3D
%3D
= 315.15 K
Now, you must convert the given mass into moles.
mol (H2SO4) = mass x MM[H2SO4]
= 870 g/ 98.0784 g/mol
= 887 mol
%3D
%3D
Find the number of moles of NH3 that will reaction with the H,SO4.
From the balanced equation, each mole of H,SO, requires 2 mol of NH
So, 8.87 mol x 2 = 17.74 mol of NH3 is needed.
Fnally use the ideal gas law to calculate the volume of ammonia that will react.
PV = nRT
nRT
V =
(17.74 mol)(0.08206
L•atm
(315.15 K)
K«mol
15.6 atm
= 29.41L
%3D
Therefore, 29.41 L of are needed.
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