QUESTION 24Pinacol isto pinacolone under acidic conditon. What are the oxidation numbers on carthon with in pinacol and pinacolone, respectivelyH3C CH,HO OH6 M H,SO,H3C.H,C CH,H,c CH,CH,pinacolpinacoloneOA reduced +1, 0O B. oxidized, +1, +2OG oxidized, 0, +2O D. oxidized, +1, 0OE. oxidized,+2. +1QUESTION 25Which of the following equations accurately represents the total vapor pressure above a boiling immiscible mixture of 2 moles af citral (P= 15 Torr) and 6 moles of water (P 745 Tor)O A. None of the answersO B. PT = (0 33)(15) + (0 67)(745)OC.Pr= (0.75)(15)+(0.25)(745)O D. PT = (2)(15) + (6)(745)!!OE PT = (0 25X15) + (0.75)(745)

Since you have posted multiple questions, we are entitled to answer the first only. 24) The reaction given is, In the above reaction, we can see that the carbon marked * in pinacol is making 3 bonds with 3 different carbon and 1 with the oxygen. Hence the oxidation state of C* in pinacol is +1 (because of oxygen only it will gain +1 charge and 0 due to the C-C bonds). And the C* in pinacolone is making 2 bonds with 2 C and 1 double-bond with the O. Hence the oxidation state of C* in pinacolone is +2 (because of oxygen only it will gain +2 charge and 0 due to the C-C bonds). Hence the oxidation state of C is increasing in the reaction. Therefore the pinacol is oxidized to pinacolone in the reaction. Hence the correct answer is option B. oxidized, +1, +2.