Phenol (C6H5OH) is partially dimerized in the solvent bromoform. When 2.58 g of phenol is dissolved in 100 g of bromoform, the bromoform freezing point is lowered by 2.37°C. Pure bromoform freezes at 8.3°C and has kf = 14.1°C kg/mol. Calculate the equilibrium constant Km for the dimerization reaction of phenol in bromoform at 6°C, assuming an ideally dilute solution.
Phenol (C6H5OH) is partially dimerized in the solvent bromoform. When 2.58 g of phenol is dissolved in 100 g of bromoform, the bromoform freezing point is lowered by 2.37°C. Pure bromoform freezes at 8.3°C and has kf = 14.1°C kg/mol. Calculate the equilibrium constant Km for the dimerization reaction of phenol in bromoform at 6°C, assuming an ideally dilute solution.
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter13: Solutions And Their Behavior
Section13.5: Colloids
Problem 2.4ACP
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Phenol (C6H5OH) is partially dimerized in the solvent bromoform. When 2.58 g of phenol is dissolved in 100 g of bromoform, the bromoform freezing point is lowered by 2.37°C. Pure bromoform freezes at 8.3°C and has kf = 14.1°C kg/mol. Calculate the equilibrium constant Km for the dimerization reaction of phenol in bromoform at 6°C, assuming an ideally dilute solution.
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