P2D.8 Use the fact that (∂U/∂V)T = a/Vm 2 for a van der Waals gas (Topic 1C) to show that μCp,m ≈ (2a/RT) − b by using the definition of μ and appropriate relations between partial derivatives. Hint: Use the approximation pVm ≈ RT when it is justifiable to do so.
P2D.8 Use the fact that (∂U/∂V)T = a/Vm 2 for a van der Waals gas (Topic 1C) to show that μCp,m ≈ (2a/RT) − b by using the definition of μ and appropriate relations between partial derivatives. Hint: Use the approximation pVm ≈ RT when it is justifiable to do so.
College Physics
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ISBN:9781305952300
Author:Raymond A. Serway, Chris Vuille
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Chapter1: Units, Trigonometry. And Vectors
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P2D.8 Use the fact that (∂U/∂V)T = a/Vm
2
for a van der Waals gas (Topic 1C)
to show that μCp,m ≈ (2a/RT) − b by using the definition of μ and appropriate
relations between partial derivatives. Hint: Use the approximation pVm ≈ RT
when it is justifiable to do so.
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