P15A.8* D. Sellmann et al. (Inorg. Chem. 36, 1397 (1997)) describe the synthesis and reactivity of the ruthenium nitrido compound [N(C,H,),][Ru(N)(S,C,H,),J. The ruthenium complex anion has the two 1,2-benzenedithiolate ligands (2) at the base of a rectangular pyramid and the nitrido ligand at the apex. Compute the mass density of the compound given that it crystallizes with an orthorhombic unit cell with a= 3.6881 nm, b= 0.9402 nm, and c = 1.7652 nm and eight formula units in each cell. The replacement of the ruthenium with osmium results in a compound with the same crystal structure and a unit cell with a volume less than 1 per cent larger. Estimate the mass density of the osmium analogue. S- 2 1,2-Benzenedithiolateion
P15A.8* D. Sellmann et al. (Inorg. Chem. 36, 1397 (1997)) describe the synthesis and reactivity of the ruthenium nitrido compound [N(C,H,),][Ru(N)(S,C,H,),J. The ruthenium complex anion has the two 1,2-benzenedithiolate ligands (2) at the base of a rectangular pyramid and the nitrido ligand at the apex. Compute the mass density of the compound given that it crystallizes with an orthorhombic unit cell with a= 3.6881 nm, b= 0.9402 nm, and c = 1.7652 nm and eight formula units in each cell. The replacement of the ruthenium with osmium results in a compound with the same crystal structure and a unit cell with a volume less than 1 per cent larger. Estimate the mass density of the osmium analogue. S- 2 1,2-Benzenedithiolateion
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![P15A.8* D. Sellmann et al. (Inorg. Chem. 36, 1397 (1997)) describe
the synthesis and reactivity of the ruthenium nitrido compound
[N(C,H,),][Ru(N)(S,C,H,),J. The ruthenium complex anion has the two
1,2-benzenedithiolate ligands (2) at the base of a rectangular pyramid and
the nitrido ligand at the apex. Compute the mass density of the compound
given that it crystallizes with an orthorhombic unit cell with a= 3.6881 nm,
b= 0.9402 nm, and c = 1.7652 nm and eight formula units in each cell. The
replacement of the ruthenium with osmium results in a compound with the
same crystal structure and a unit cell with a volume less than 1 per cent larger.
Estimate the mass density of the osmium analogue.
S-
2 1,2-Benzenedithiolateion](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe88bd3c5-4e71-4d62-bfb2-583da5b980bf%2Fc0674d21-10ef-4f75-8d24-b3eca5c04fad%2Fpdrgo1a.png&w=3840&q=75)
Transcribed Image Text:P15A.8* D. Sellmann et al. (Inorg. Chem. 36, 1397 (1997)) describe
the synthesis and reactivity of the ruthenium nitrido compound
[N(C,H,),][Ru(N)(S,C,H,),J. The ruthenium complex anion has the two
1,2-benzenedithiolate ligands (2) at the base of a rectangular pyramid and
the nitrido ligand at the apex. Compute the mass density of the compound
given that it crystallizes with an orthorhombic unit cell with a= 3.6881 nm,
b= 0.9402 nm, and c = 1.7652 nm and eight formula units in each cell. The
replacement of the ruthenium with osmium results in a compound with the
same crystal structure and a unit cell with a volume less than 1 per cent larger.
Estimate the mass density of the osmium analogue.
S-
2 1,2-Benzenedithiolateion
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