1.K₂[Co(dme)(bpy) (NCS)Cl₂]i.ii.iii.iv.V.vi.vii.viii.ix.X.Coordination compoundDetermine the oxidation stateof central metal andcoordination number of thecomplex.Write down the quantumnumber of the outmost orbitalof the central metal.Determine the magneticbehavior of the central metal.Name the compound above.and draw a structure of thecomplexes.Highlight the donor atom andgive the likely modes ofbonding of the ligand dme(e.g: monodentate)If dme ligand has beenreplaced by anion ligand acacand bpy ligand has beenreplaced by any anionicmonodentate ligand, nameand draw a structure of a newcoordination compound.Give an example of a ligandthat has the same modes ofbonding with dme and bpy.Determine whether thecomplex follows the18-electron rule or not.Sketch the structure of thetwo linkage isomers of thecomplexK₂[Co(dme)(bpy) (NCS)CI₂].Does this complex(K. [Co(dme)(bpy) (NCS)CI,])have the potential to formgeometrical isomers? if so,sketch the isomer involved.

“Since you have posted a question with multiple sub-parts, we will solve first three subparts for…

1. K₂[Co(dme)(bpy)(NCS)CI₂] i. ii. iii. Coordination compound Determine the oxidation state of central metal and coordination number of the complex. Write down the quantum number of the outmost orbital of the central metal. Determine the magnetic behavior of the central metal.

1. K₂[Co(dme)(bpy)(NCS)CI₂] i. ii. iii. Coordination compound Determine the oxidation state of central metal and coordination number of the complex. Write down the quantum number of the outmost orbital of the central metal. Determine the magnetic behavior of the central metal.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

1.
K₂[Co(dme)(bpy) (NCS)Cl₂]
i.
ii.
iii.
iv.
V.
vi.
vii.
viii.
ix.
X.
Coordination compound
Determine the oxidation state
of central metal and
coordination number of the
complex.
Write down the quantum
number of the outmost orbital
of the central metal.
Determine the magnetic
behavior of the central metal.
Name the compound above.
and draw a structure of the
complexes.
Highlight the donor atom and
give the likely modes of
bonding of the ligand dme
(e.g: monodentate)
If dme ligand has been
replaced by anion ligand acac
and bpy ligand has been
replaced by any anionic
monodentate ligand, name
and draw a structure of a new
coordination compound.
Give an example of a ligand
that has the same modes of
bonding with dme and bpy.
Determine whether the
complex follows the
18-electron rule or not.
Sketch the structure of the
two linkage isomers of the
complex
K₂[Co(dme)(bpy) (NCS)CI₂].
Does this complex
(K. [Co(dme)(bpy) (NCS)CI,])
have the potential to form
geometrical isomers? if so,
sketch the isomer involved.

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