Bridging structures are quite common in coordination compounds. In this kind of structure, the ligand charge is split between the number of metals that it is bonded. For example, if a ligand with charge 2+ is bridging two metals, each metal will “feel” a 1+ charge. What is the oxidation state, and the number of d- electrons for each ruthenium atom in the structure below?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

 Bridging structures are quite common in coordination compounds. In this kind of structure, the ligand
charge is split between the number of metals that it is bonded. For example, if a ligand with charge 2+ is
bridging two metals, each metal will “feel” a 1+ charge. What is the oxidation state, and the number of d-
electrons for each ruthenium atom in the structure below? 

 

The image is a structural diagram of a chemical compound involving ruthenium and chlorine atoms. The structure features the following components:

1. **Ruthenium Atoms (Ru):** There are two ruthenium (Ru) atoms in the structure, each forming the center of coordination environments.

2. **Chlorine Atoms (Cl):** Three chlorine atoms are directly bonded to the ruthenium atoms. Each ruthenium atom is bonded to one terminal chlorine atom, and there is one bridging chlorine atom connecting the two ruthenium centers.

3. **Cyclopentadienyl Rings (Cp):** Each ruthenium atom is also bonded to a cyclopentadienyl (Cp) ring, depicted as a pentagon, typical of metallocene-type structures.

4. **Bonding:** The bonds between the atoms vary, with single lines denoting single bonds and the dotted lines indicating coordination bonds that are part of the coordination complex.

This coordination compound exemplifies a dinuclear metal complex with a bridging ligand, in this case, a chlorine atom. This type of structure is significant in the study of organometallic chemistry due to its unique bonding situations and potential catalytic applications.
Transcribed Image Text:The image is a structural diagram of a chemical compound involving ruthenium and chlorine atoms. The structure features the following components: 1. **Ruthenium Atoms (Ru):** There are two ruthenium (Ru) atoms in the structure, each forming the center of coordination environments. 2. **Chlorine Atoms (Cl):** Three chlorine atoms are directly bonded to the ruthenium atoms. Each ruthenium atom is bonded to one terminal chlorine atom, and there is one bridging chlorine atom connecting the two ruthenium centers. 3. **Cyclopentadienyl Rings (Cp):** Each ruthenium atom is also bonded to a cyclopentadienyl (Cp) ring, depicted as a pentagon, typical of metallocene-type structures. 4. **Bonding:** The bonds between the atoms vary, with single lines denoting single bonds and the dotted lines indicating coordination bonds that are part of the coordination complex. This coordination compound exemplifies a dinuclear metal complex with a bridging ligand, in this case, a chlorine atom. This type of structure is significant in the study of organometallic chemistry due to its unique bonding situations and potential catalytic applications.
Expert Solution
Step 1

Chemistry homework question answer, step 1, image 1

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Atomic Structure and Spectra
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY