Ozone in the upper atmosphere is decomposed by nitro- gen oxide through the reaction 03 + NO →02 + NO2 The experimental rate expression for this reaction is rate = k[O3 ][NO] Which, if any, of the following mechanisms are consistent with the observed rate expression? (a) O3 + NO –→0+NO; 0 + 03 →2 02 NO3 + NO → 2 NO2 (b) O3 + NO – 02 NO2 (c) NO+ NO=N2O2 N2O2 + O; → NO2 + 2 O2 (slow) (fast) (fast) (slow) (fast equilibrium) (slow)
Ozone in the upper atmosphere is decomposed by nitro- gen oxide through the reaction 03 + NO →02 + NO2 The experimental rate expression for this reaction is rate = k[O3 ][NO] Which, if any, of the following mechanisms are consistent with the observed rate expression? (a) O3 + NO –→0+NO; 0 + 03 →2 02 NO3 + NO → 2 NO2 (b) O3 + NO – 02 NO2 (c) NO+ NO=N2O2 N2O2 + O; → NO2 + 2 O2 (slow) (fast) (fast) (slow) (fast equilibrium) (slow)
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question
![Ozone in the upper atmosphere is decomposed by nitro-
gen oxide through the reaction
03 + NO →02 + NO2
The experimental rate expression for this reaction is
rate = k[O3 ][NO]
Which, if any, of the following mechanisms are consistent
with the observed rate expression?
(a) O3 + NO –→0+NO;
0 + 03 →2 02
NO3 + NO → 2 NO2
(b) O3 + NO – 02 NO2
(c) NO+ NO=N2O2
N2O2 + O; → NO2 + 2 O2
(slow)
(fast)
(fast)
(slow)
(fast equilibrium)
(slow)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc7747577-82b7-4e41-b29b-581e852cd022%2Fd9a98737-0396-41cc-a962-4e631f49e79d%2F33jheo9.png&w=3840&q=75)
Transcribed Image Text:Ozone in the upper atmosphere is decomposed by nitro-
gen oxide through the reaction
03 + NO →02 + NO2
The experimental rate expression for this reaction is
rate = k[O3 ][NO]
Which, if any, of the following mechanisms are consistent
with the observed rate expression?
(a) O3 + NO –→0+NO;
0 + 03 →2 02
NO3 + NO → 2 NO2
(b) O3 + NO – 02 NO2
(c) NO+ NO=N2O2
N2O2 + O; → NO2 + 2 O2
(slow)
(fast)
(fast)
(slow)
(fast equilibrium)
(slow)
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