17.3 Acid- and base-catalysed reactions are common in organic transformations. (a) Deduce the rate law of the base-catalysed reaction in which AH goes to products according to the following scheme AH +Ba BH* + A¯ A + AH , product (rate-determining) (b) Deduce the rate law of the acid-catalysed reaction in which HA goes to products according to the following scheme НА + Н" НАН" kb НАН' + В → BH* + AH (rate-determining)

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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17.3 Acid- and base-catalysed reactions are common in organic
transformations. (a) Deduce the rate law of the base-catalysed reaction in
which AH goes to products according to the following scheme
AH +Ba
BH* + A¯
A + AH , product (rate-determining)
(b) Deduce the rate law of the acid-catalysed reaction in which HA goes to
products according to the following scheme
НА + Н"
НАН"
kb
НАН' + В
→ BH* + AH (rate-determining)
Transcribed Image Text:17.3 Acid- and base-catalysed reactions are common in organic transformations. (a) Deduce the rate law of the base-catalysed reaction in which AH goes to products according to the following scheme AH +Ba BH* + A¯ A + AH , product (rate-determining) (b) Deduce the rate law of the acid-catalysed reaction in which HA goes to products according to the following scheme НА + Н" НАН" kb НАН' + В → BH* + AH (rate-determining)
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