obre Texts Born Haber and AHrxn Lys- 18. Calculate the lattice energy for LiBr(s) given the following: () sublimation energy for Li(s) AH, for Br(g) first ionization energy of Li(g) electron affinity of Br(g) enthalpy of formation of LiBr(s) a. 107 kJ/mol b. 195 kJ/mol c. -546 kJ/mol d. -809 kJ/mol e. none of these +166 kJ/mol +97 kJ/mol (1) Ma 7 Li +520. kJ/mol -325 kJ/mol -351 kJ/mol AH+166 kJ/mol LI(g) 7 Lit+eAH=+520 KJ/mol Br₂(g) → 2Br AH = +97 kJ/mol Br+e¬Br² XH = -325 10/m01 2kLit | Br¬7 LiBr AH = -351 kJ/mo 2 ΔΗ-Σ
Types of Chemical Bonds
The attractive force which has the ability of holding various constituent elements like atoms, ions, molecules, etc. together in different chemical species is termed as a chemical bond. Chemical compounds are dependent on the strength of chemical bonds between its constituents. Stronger the chemical bond, more will be the stability in the chemical compounds. Hence, it can be said that bonding defines the stability of chemical compounds.
Polarizability In Organic Chemistry
Polarizability refers to the ability of an atom/molecule to distort the electron cloud of neighboring species towards itself and the process of distortion of electron cloud is known as polarization.
Coordinate Covalent Bonds
A coordinate covalent bond is also known as a dative bond, which is a type of covalent bond. It is formed between two atoms, where the two electrons required to form the bond come from the same atom resulting in a semi-polar bond. The study of coordinate covalent bond or dative bond is important to know about the special type of bonding that leads to different properties. Since covalent compounds are non-polar whereas coordinate bonds results always in polar compounds due to charge separation.
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Born Haber and AHxn
7 Li
18. Calculate the lattice energy for LiBr(s) given the following:
sublimation energy for Li(s)
+166 kJ/mol
(12) L1 (9) AH = +166 kJ/mc)
(9) 7 Lit + e²AH= +520 KJ/mol
+97 kJ/mol
+520. kJ/mol
A-325 kJ/mol
-351 kJ/mol B₁ (9)→2Br AH=+97 kJ/mol
BITCĐBr XH= -325 mol
oliol
Lit | Br¬LiBr AH = -351 kJ/mmcl
ΔΗ-Σ
AH, for Br(g)
first ionization energy of Li(g)
electron affinity of Br(g)
enthalpy of formation of LiBr(s)
a. 107 kJ/mol
b. 195 kJ/mol
c. -546 kJ/mol
d. -809 kJ/mol
e. none of
these
1
(10)
EXTR
ALL 20
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It is based on the concept of lattice energy
Here we are required to find the lattice energy of LiBr from the data given
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