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o The following elementary gas-phase reaction takes place in a constant- pressure isothermal vessel (1 atm, 25°C): hv CH, (g) + 2Cl, (g)- →CH,Cl,(g,l)+ 2HCI(g) o k = 0.2 dm/(s•mol²) at 25°C (estimated) O CH,Cl,: Pvap = 400 mm Hg (53 kPa) at 25°C. Evaluate -r, in terms of conversion of chlorine, the specific reaction rate, and the initial chlorine concentration.

o The following elementary gas-phase reaction takes place in a constant- pressure isothermal vessel (1 atm, 25°C): hv CH, (g) + 2Cl, (g)- →CH,Cl,(g,l)+ 2HCI(g) o k = 0.2 dm/(s•mol²) at 25°C (estimated) O CH,Cl,: Pvap = 400 mm Hg (53 kPa) at 25°C. Evaluate -r, in terms of conversion of chlorine, the specific reaction rate, and the initial chlorine concentration.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Example o The following elementary gas-phase reaction takes place in a constant- pressure isothermal vessel (1 atm, 25°C): hv CH, (g) + 2Cl, (g)– >CH,Cl, (g,l) + 2HCII(g) o k = 0.2 dm/(s•mol2) at 25°C (estimated) O CH,Cl2: Pvap = 400 mm Hg (53 kPa) at 25°C. Evaluate -ra in terms of conversion of chlorine, the specific reaction rate, and the initial chlorine concentration.
Transcribed Image Text:Example o The following elementary gas-phase reaction takes place in a constant- pressure isothermal vessel (1 atm, 25°C): hv CH, (g) + 2Cl, (g)– >CH,Cl, (g,l) + 2HCII(g) o k = 0.2 dm/(s•mol2) at 25°C (estimated) O CH,Cl2: Pvap = 400 mm Hg (53 kPa) at 25°C. Evaluate -ra in terms of conversion of chlorine, the specific reaction rate, and the initial chlorine concentration.
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