O Draw all stereoisomers for the following molecules; indicate the stereochemic interrelationships (enantiomer, diastereomer, or meso) for all its possible pairs. 4) H;C CH3 (b HO CH3 OH CI Но- OH
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- Indicate the relationship between each pair. Choose from: configurational stereoisomers,conformers, constitutional isomers, or different formulas (Each term is used at least twice.)5. Given the following structure: (a) Draw all the stereoisomers; CH2 OH (b) Identify all of the enantiomeric and diastereomeric pairs; (c) Assign R or S configuration at each asymmetric carbon for each structure. Justify your assignments for the original structure (above).8. Identify the stereochemical relationship between the structural pairs shown below as (A) identical structures that are not meso; (B) identical structures that ARE meso; (C) structures that are enantiomers; or (D) structures that are diastereomers. a) b) H3C c) CH3 Br H. CH3 Br Br CH3 H. CI Holl H Cill Cl- CH3 Br H. CI CH3 HO. H. H3C Cl H3C- H- H. CH3 Cl a) b) c) 9. Identify the stereochemical relationship between the structural pairs shown below as (A) identical structures that are not meso; (B) identical structures that ARE meso; (C) structures that are enantiomers; or (D) structures that are diastereomers. a) b) c) CH2CH3 NH2 HO CH3 H3C. CH3 Cl HO H;C CH2CH3 F. F H;C. CI H H,N -CH3 CH3 NH2 H3C Br H2N C1 H3C CH3 CH3 H;CH,C- Cl F H. H Br CH,CH3 CH3 a) b) c)
- 2. Identify the type of stereoisomerism in each of the following molecules and draw the stereoisomer pair. (a) CH;CH=CHCOH (b) CgH;CH2CH(NH2)CH33. For each of the following pairs of structures identify the stereochemical relationship as identical, constitutional isomers, enantiomers or diastereomers. (^- a) b) SH H₂C SH CH 3 ၀င်း H₂C CH3 HÇI CI- CI CI CI Give the structures of the two stereoisomers for which the chair interconversion results in identical molecules.
- Among the following stucture given below, the one that cowespond) to the Imost stable conformation of compound A is ! Explain your answer. Me compound A Arial 01H Me Me Me equotona OHFOR/ • Ang • Tors • Ster O what structural cfects do the ff. opds exhivit? Enumate all. Then idenbify the pred ommant effect. (a) 언 NO2 (c) 1.4 S Elec5. Consider the following pairs of structures. Identify the relationship between them (enantiomers, diastereomers, or identical compounds. H3C OH H₂C HOITY H CH₂OH HO HO C,, CO₂H вой HOH2C CH₂ OH H OH H OH Н HO H H COzH Br Д H3C Br H₂CH₂C CI H CHO CH3 I CH3 OH HO Н HO... HO C OHC Н H3C, Bell!! H CO₂H Н.С CH₂OH H OH H OH HO H CH₂ CO₂H HỌ,H CH₂CH3 CH3 CI CH₂OH Br
- 7. (Identify the following compounds as chiral, achiral, or mesoQ2 Give the stereochemical relationships between each pair of structures. Examples are same compound, structural isomers, enantiomers, diastereomers fa CH. OH HO- OR HO CH, CH. CH,ОН ОН В For the following molecule B Give the number of stereoisomerism elements :