Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Complete the synthesis reaction showing curved arrows and mechanisms for each reaction.
![НООС
HO
2.
H2
1. p-Toluenesulfonic acid
Oppenauer
Lindlar Catalyst
2. Н2, Pа/c
Oxidation
HO](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fda9c8b35-666b-48ab-a806-a1fce889b83d%2F2c0dd9a5-683a-4e6e-b220-f245e7cf588b%2F7krg6sm_processed.png&w=3840&q=75)
Transcribed Image Text:НООС
HO
2.
H2
1. p-Toluenesulfonic acid
Oppenauer
Lindlar Catalyst
2. Н2, Pа/c
Oxidation
HO
Expert Solution
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Step 1
For the above organic synthesis, the following transformations must be known:
1. H2 in presence of Lindlar's catalyst reduces alkyne to cis-alkene.
2. p-Toluenesulfonic acid reacts with 3o alcohol to form tosylate and elimination occurs.
3. H2 , Pd/C reduces alkenes to alkanes.
4. Oppenauer Oxidation is a simple method for selectively oxidizing 2o acohols to ketones.
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