Mn(g) → Mn“(g)+2 e¯ Mn(s) → Mn(g) S(s) → S(g) S(g) +2 e→ s²(g) Mn (g) + S(g)→ MnS(s) Mn(s) + S(s) → MnS(s) b. AH=+2230 kJ/mole AH= AH= +264 kJ/mole AH=+246 kJ/mole AH=-3176 kJ/mole AH=-212 kJ/mole

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Answer letter B only

1. Use a Born-Haber Cycle to calculate the missing AH (bold reaction) of the following:
а.
AH2660 Emole
Be(g)
ALL
AĦ
+107 kJ/mole
Beo 2 IT(9
Bel:(s)
AH
Bets) L(s)
208 KJ/mole Beb,
Mn(g) → Mn“(g) + 2 e
Mn(s) → Mn(g)
S(s) → S(g)
S(g) +2 e→ s(g)
Mn* (g) + s (g) → MnS(s)
Mn(s) + S(s) →> MnS(s)
b.
AH= +2230 kJ/mole
AH=
AH=+264 kJ/mole
AH=+246 kJ/mole
AH=-3176 kJ/mole
AH=-212 kJ/mole
Transcribed Image Text:1. Use a Born-Haber Cycle to calculate the missing AH (bold reaction) of the following: а. AH2660 Emole Be(g) ALL AĦ +107 kJ/mole Beo 2 IT(9 Bel:(s) AH Bets) L(s) 208 KJ/mole Beb, Mn(g) → Mn“(g) + 2 e Mn(s) → Mn(g) S(s) → S(g) S(g) +2 e→ s(g) Mn* (g) + s (g) → MnS(s) Mn(s) + S(s) →> MnS(s) b. AH= +2230 kJ/mole AH= AH=+264 kJ/mole AH=+246 kJ/mole AH=-3176 kJ/mole AH=-212 kJ/mole
Expert Solution
Step 1

     

 

Mn (g) Mn 2+ (g) + 2e-
 +2230 kJ/mole Ionization energy (IE)
Mn (s) Mn (g) H1sublimation (of Mn)
S (s)  S (g)  +264 kJ/mole   H2sublimation (of S)
S(g) + 2e-  S2- (g)  +246 kJ/mole  electron affinity (EA)
Mn2-(g) + S2-(g)  MnS (s) -3176 kJ/mole Lattice energy (U)
Mn(s) + S(s)  MnS (s)  -212 kJ/mole Hformation 

 

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